{"id":58,"date":"2016-03-08T13:29:55","date_gmt":"2016-03-08T13:29:55","guid":{"rendered":"http:\/\/nakayama.web.nitech.ac.jp\/jp\/?page_id=58"},"modified":"2025-09-22T04:07:08","modified_gmt":"2025-09-22T04:07:08","slug":"%e5%ae%9f%e9%a8%93%e7%b3%bb%e7%a0%94%e7%a9%b6-2","status":"publish","type":"page","link":"http:\/\/nakayama.web.nitech.ac.jp\/jp\/%e7%a0%94%e7%a9%b6%e6%b4%bb%e5%8b%95\/%e5%ae%9f%e9%a8%93%e7%b3%bb%e7%a0%94%e7%a9%b6-2\/","title":{"rendered":"\u5b9f\u9a13\u7cfb\u7814\u7a76"},"content":{"rendered":"<h1><b>\u25a0<\/b>\u3000<b>\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306e\u6750\u6599\u7814\u7a76\uff08\u5b9f\u9a13\u7cfb\uff09<\/b><\/h1>\n<p><b>\u7814\u7a76\u80cc\u666f<img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-116 alignright\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Coin2.png\" alt=\"Coin2\" width=\"155\" height=\"292\" \/><br \/>\n<\/b><span style=\"color: #ff0000;\"><span style=\"color: #000000;\">\u3000\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306f\u9ad8\u30a8\u30cd\u30eb\u30ae\u30fc\u5bc6\u5ea6\u3067\u7279\u5fb4\u3065\u3051\u3089\u308c\u308b\u96fb\u6c17\u30a8\u30cd\u30eb\u30ae\u30fc\u8caf\u8535\u30c7\u30d0\u30a4\u30b9\u3067\u3059\u3002<\/span><\/span>\u3064\u307e\u308a\u3001\u5927\u91cf\u306e\u96fb\u6c17\u30a8\u30cd\u30eb\u30ae\u30fc\u3092\u300c\u3088\u308a\u8efd\u304f\u300d\u3001\u300c\u3088\u308a\u5c0f\u3055\u3044\u300d\u96fb\u6c60\u306e\u4e2d\u306b\u84c4\u3048\u308b\u3053\u3068\u304c\u3067\u304d\u3001\u4f55\u5ea6\u3082\u5145\u653e\u96fb\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u30c7\u30d0\u30a4\u30b9\u3067\u3059<br 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href=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/%E7%A0%94%E7%A9%B6%E6%B4%BB%E5%8B%95\/%E5%AE%9F%E9%A8%93%E7%B3%BB%E7%A0%94%E7%A9%B6\/\">\u8a08\u7b97\u7cfb\u7814\u7a76<\/a>\u3082\u884c\u3063\u3066\u3044\u307e\u3059\uff09<\/p>\n<p>\u3010\u7814\u7a76\u4f8b\u3011<br \/>\n<a href=\"#a05\">\u84c4\u96fb\u6c60\u6750\u6599\u306e\u6750\u6599\u7269\u6027\u8a55\u4fa1\u30fb\u65b0\u7269\u8cea\u63a2\u7d22\u306b\u95a2\u3059\u308b\u7814\u7a76<\/a><br \/>\n<a href=\"#a01\">\u96fb\u6975\u53cd\u5fdc\u306e\u7d20\u904e\u7a0b\u89e3\u6790<\/a><br \/>\n<a href=\"#a02\">\u5168\u56fa\u4f53\u30ea\u30c1\u30a6\u30e0\u30dd\u30ea\u30de\u30fc\u96fb\u6c60\u306e\u958b\u767a<\/a><br \/>\n<a href=\"#a03\">\u53cd\u5fdc\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u6e2c\u5b9a<\/a><br \/>\n<a href=\"#a04\">\u96fb\u6975\u6750\u6599\u306e\u7d50\u6676\u30fb\u96fb\u5b50\u69cb\u9020\u89e3\u6790<\/a><\/p>\n<h6><strong>\u84c4\u96fb\u6c60\u6750\u6599\u306e\u6750\u6599\u7269\u6027\u8a55\u4fa1\u30fb\u65b0\u7269\u8cea\u63a2\u7d22\u306b\u95a2\u3059\u308b\u7814\u7a76<a name=\"a05\"><\/a><\/strong><\/h6>\n<p>\u3088\u308a\u512a\u308c\u305f\u84c4\u96fb\u6c60\u6750\u6599\u3092\u69cb\u6210\u3059\u308b\u30bb\u30e9\u30df\u30c3\u30af\u30b9\u6750\u6599\u3092\u898b\u51fa\u3059\u305f\u3081\u306b\u3001\uff11\uff09\u6750\u6599\u7269\u6027\u306e\u6e2c\u5b9a\u8a55\u4fa1\u306b\u57fa\u3065\u304f\u6750\u6599\u8a2d\u8a08\u6307\u91dd\u306e\u78ba\u7acb\u3068\u3001\uff12\uff09\u6750\u6599\u8a08\u7b97\u3084\u30de\u30c6\u30ea\u30a2\u30eb\u30ba\u30fb\u30a4\u30f3\u30d5\u30a9\u30de\u30c6\u30a3\u30af\u30b9\u3068\u9023\u643a\u3057\u305f\u5b9f\u9a13\u7684\u306a\u65b0\u6750\u6599\u5408\u6210\u30fb\u7d44\u6210\u6700\u9069\u5316\u3092\u5b9f\u65bd\u3057\u3066\u3044\u307e\u3059\u3002<\/p>\n<p><strong>\u2605\u4f8b\u3000\u30cf\u30a4\u30b9\u30eb\u30fc\u30d7\u30c3\u30c8\u8a08\u7b97\u306b\u3088\u308b\u65b0\u898f\u9ad8\u901f\u30ca\u30c8\u30ea\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u6b63\u6975\u6750\u6599\u306e\u767a\u898b \uff08\u53c2\u8003\u6587\u732e\u3000<a href=\"https:\/\/doi.org\/10.1038\/s41598-018-35608-9\">2018<\/a>\uff09<\/strong><\/p>\n<p>\u7d50\u6676\u69cb\u9020\u30c7\u30fc\u30bf\u30d9\u30fc\u30b9\u306b\u5bfe\u3059\u308b\u30a4\u30aa\u30f3\u4f1d\u5c0e\u306e\u6d3b\u6027\u5316\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u7db2\u7f85\u8a08\u7b97\u306b\u3088\u308a\u3001\u52b9\u7387\u7684\u306b\u65b0\u898f\u306a\u9ad8\u901f\u5145\u653e\u96fb\u304c\u53ef\u80fd\u306a\u30ca\u30c8\u30ea\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u6b63\u6975\u6750\u6599Na<sub>2<\/sub>V<sub>3<\/sub>O<sub>7<\/sub>\u3092\u63d0\u6848\u3057\u305f\u3002\u5f53\u8a72\u7269\u8cea\u3092\u5b9f\u969b\u306b\u5408\u6210\u3057\u30ca\u30c8\u30ea\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u3092\u7d44\u307f\u7acb\u3066\u3001\u5b9f\u9a13\u7684\u306b\u96fb\u6c60\u7279\u6027\u3092\u8a55\u4fa1\u3057\u305f\u3068\u3053\u308d\u300110C (6\u5206\u3067\u6e80\u5145\u96fb\u30fb\u6e80\u653e\u96fb\u3059\u308b\u3088\u3046\u306a\u5145\u653e\u96fb\u901f\u5ea6\uff09\u3067\u3082\u5b89\u5b9a\u3057\u305f\u30b5\u30a4\u30af\u30eb\u3092\u3059\u308b\u9ad8\u3044\u30ec\u30fc\u30c8\u7279\u6027\u3092\u793a\u3057\u305f\u3002\u307e\u305f\u3001\u96fb\u6c17\u5316\u5b66\u6e2c\u5b9a\u3068\u7b2c\u4e00\u539f\u7406\u8a08\u7b97\u3092\u7d44\u307f\u5408\u308f\u305b\u3001\u66f4\u306a\u308b\u9ad8\u6027\u80fd\u5316\u306b\u5411\u3051\u305f\u8a2d\u8a08\u6307\u91dd\u3092\u660e\u3089\u304b\u306b\u3057\u305f\u3002(\u62c5\u5f53: \u8c37\u7aef)<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-1431\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/Figure-\u30b3\u30d4\u30fc.jpg\" alt=\"Figure - \u30b3\u30d4\u30fc\" width=\"1280\" height=\"960\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/Figure-\u30b3\u30d4\u30fc.jpg 1280w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/Figure-\u30b3\u30d4\u30fc-300x225.jpg 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/Figure-\u30b3\u30d4\u30fc-768x576.jpg 768w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/Figure-\u30b3\u30d4\u30fc-1024x768.jpg 1024w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/Figure-\u30b3\u30d4\u30fc-400x300.jpg 400w\" sizes=\"auto, (max-width: 1280px) 100vw, 1280px\" \/><\/p>\n<h6><\/h6>\n<p><b>\u2605\u7814\u7a76\u4f8b\u3000\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u578b\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u5c0e\u96fb\u6027\u9178\u5316\u7269<\/b><\/p>\n<p>\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u5c0e\u96fb\u6027\u9178\u5316\u7269\u3068\u3057\u3066\u3001\u3082\u3063\u3068\u3082\u9ad8\u3044\u30a4\u30aa\u30f3\u5c0e\u96fb\u6027\u3092\u793a\u3059\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u578b\u9178\u5316\u7269\u6750\u6599\u306e\u30a4\u30aa\u30f3\u5c0e\u96fb\u6027\u3092\u7d50\u6676\u69cb\u9020\u89e3\u6790\u306e\u89b3\u70b9\u304b\u3089\u7814\u7a76\u3057\u3066\u3044\u308b\u3002\u305f\u3068\u3048\u3070\u3001\u4e00\u822c\u306b\u306f\u683c\u5b50\u30b5\u30a4\u30ba\u304c\u5927\u304d\u304f\u306a\u308c\u3070\u30a4\u30aa\u30f3\u5c0e\u96fb\u6027\u3082\u9ad8\u304f\u306a\u308b\u3068\u8003\u3048\u3089\u308c\u308b\u304c\u3001\u6642\u3068\u3057\u3066\u305d\u306e\u3088\u3046\u306a\u50be\u5411\u306b\u4e00\u81f4\u3057\u306a\u3044\u6750\u6599\u3082\u5b58\u5728\u3059\u308b\u3002\u3053\u306e\u3088\u3046\u306a\u7279\u7570\u306a\u6319\u52d5\u3092\u793a\u3059\u6750\u6599\u306e\u5c40\u6240\u69cb\u9020\u3092EXAFS\u3067\u8abf\u3079\u305d\u306e\u76f8\u95a2\u3092\u8abf\u3079\u305f\u3002\u307e\u305f\u3001\u30a4\u30aa\u30f3\u5c0e\u96fb\u7387\u306e\u6e29\u5ea6\u4f9d\u5b58\u6027\u306f\u4e00\u822c\u306b\u306f\u30a2\u30ec\u30cb\u30a6\u30b9\u5247\u306b\u5f93\u3046\u304c\u3001\u7279\u306b\u76f8\u8ee2\u79fb\u306a\u3069\u7121\u304f\u3066\u3082\u9ad8\u6e29\u90e8\u3067\u30a2\u30ec\u30cb\u30a6\u30b9\u76f4\u7dda\u306b\u5c48\u66f2\u304c\u89b3\u6e2c\u3055\u308c\u308b\u30b1\u30fc\u30b9\u304c\u5b58\u5728\u3059\u308b\u3002\u3053\u306e\u3088\u3046\u306a\u73fe\u8c61\u306b\u3064\u3044\u3066\u3082\u4e2d\u6027\u5b50\u56de\u6298\u6e2c\u5b9a\u3067\u691c\u8a0e\u306a\u3069\u3092\u884c\u3063\u3066\u3044\u308b\u3002\u6700\u8fd1\u3067\u306f\u5b9f\u9a13\u3060\u3051\u3067\u306f\u306a\u304f\u8a08\u7b97\u5316\u5b66\u306b\u3088\u308b\u30a2\u30d7\u30ed\u30fc\u30c1\u3082\u4f75\u7528\u3057\u3066\u7814\u7a76\u3092\u5c55\u958b\u3057\u3066\u3044\u308b\uff08\u53c2\u8003\u6587\u732e<a href=\"http:\/\/www.rsc.org\/publishing\/journals\/JM\/article.asp?doi=b200310d\">2002-1<\/a>, <a href=\"http:\/\/link.aip.org\/link\/?APPLAB\/81\/2977\/1\">2002-2<\/a>, <a href=\"http:\/\/link.aip.org\/link\/?APPLAB\/84\/4227\/1\">2004<\/a>)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-330\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/pero_ion1.jpg\" alt=\"pero_ion1\" width=\"238\" height=\"234\" \/><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-328\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/pero_ion_3.jpg\" alt=\"pero_ion_3\" width=\"254\" height=\"301\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/pero_ion_3.jpg 254w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/pero_ion_3-253x300.jpg 253w\" sizes=\"auto, (max-width: 254px) 100vw, 254px\" \/><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-329\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/pero_ion_4.png\" alt=\"pero_ion_4\" width=\"481\" height=\"279\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/pero_ion_4.png 481w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/pero_ion_4-300x174.png 300w\" sizes=\"auto, (max-width: 481px) 100vw, 481px\" \/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-382\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/pero_ion_2-1.gif\" alt=\"pero_ion_2\" width=\"429\" height=\"398\" \/><\/p>\n<p><strong>\u2605\u4f8b\u3000\u5168\u56fa\u4f53Li\u91d1\u5c5e\u96fb\u6c60\u306b\u3080\u3051\u305f\u9ad8\u5909\u5f62\u80fd\u3092\u6709\u3059\u308b\u5869\u5316\u7269\u56fa\u4f53\u96fb\u89e3\u8cea\u6750\u6599\u306e\u63a2\u7d22 (\u53c2\u8003\u6587\u732e <a href=\"https:\/\/pubs.acs.org\/doi\/full\/10.1021\/acsmaterialslett.0c00127\">2020<\/a>)<\/strong><\/p>\n<p>\u9ad8\u30a8\u30cd\u30eb\u30ae\u30fc\u5bc6\u5ea6Li\u91d1\u5c5e\u96fb\u6975\u306e\u5b9f\u73fe\u306b\u5411\u3051\u3001\u30c7\u30f3\u30c9\u30e9\u30a4\u30c8\u3092\u6291\u5236\u3059\u308b\u9ad8\u5bc6\u5ea6\u56fa\u4f53\u96fb\u89e3\u8cea\u304c\u6c42\u3081\u3089\u308c\u308b\u3002\u672c\u7814\u7a76\u3067\u306f\u3001\u5727\u7c89\u51e6\u7406\u306e\u307f\u306b\u3088\u3063\u3066Li\u30c7\u30f3\u30c9\u30e9\u30a4\u30c8\u3092\u6291\u5236\u3067\u304d\u308b\u9ad8\u5909\u5f62\u80fd\u56fa\u4f53\u96fb\u89e3\u8cea\u3092\u63a2\u7d22\u3059\u308b\u305f\u3081\u306b\u3001Li+\u30a4\u30aa\u30f3\u3068\u306e\u30af\u30fc\u30ed\u30f3\u76f8\u4e92\u4f5c\u7528\u304c\u5f31\u304f\u5206\u6975\u7387\u306e\u9ad8\u3044Cl\u3092\u542b\u3080Li\u5316\u5408\u7269\u306b\u6ce8\u76ee\u3057\u305f\u3002\u30c7\u30fc\u30bf\u30d9\u30fc\u30b9\u306b\u5b58\u5728\u3059\u308bLi-Cl\u5316\u5408\u7269\u306b\u5bfe\u3057\u3066\u3001\u30a4\u30aa\u30f3\u4f1d\u5c0e\u5ea6\u3001\u5909\u5f62\u80fd\u3001\u71b1\u529b\u5b66\u7684\u5b89\u5b9a\u6027\u306e\u6307\u6a19\u3068\u3057\u3066\u3001Li+\u30a4\u30aa\u30f3\u79fb\u52d5\u30a8\u30cd\u30eb\u30ae\u30fc\u3001\u30d0\u30eb\u30af\u5f3e\u6027\u7387\u3001\u5206\u89e3\u30a8\u30cd\u30eb\u30ae\u30fc\u304c\u7db2\u7f85\u8a08\u7b97\u3055\u308c\u305f\u3002\u305d\u306e\u4e2d\u3067\u30013\u3064\u306e\u6307\u6a19\u3068\u3082\u6709\u671b\u306a\u5024\u3092\u793a\u3059\u5358\u659c\u6676LiAlCl4\u306b\u6ce8\u76ee\u3057\u305f\u3002XRD\u30687Li-MAS NMR\u306e\u6e2c\u5b9a\u304b\u3089\u3001\u30e1\u30ab\u30ce\u30b1\u30df\u30ab\u30eb\u5408\u6210\u3055\u308c\u305fLiAlCl4\u306f\u5358\u659c\u6676\u30db\u30b9\u30c8\u69cb\u9020\u3092\u6301\u3061\u3001\u5c11\u91cf\u306eLi (2.5%) \u304c\u8a08\u7b97\u3067\u793a\u3055\u308c\u305f\u9ad8\u30a4\u30aa\u30f3\u4f1d\u5c0e\u7d4c\u8def\u4e0a\u306e\u6e96\u5b89\u5b9a\u30b5\u30a4\u30c8\u3092\u5360\u6709\u3057\u3066\u3044\u308b\u3053\u3068\u304c\u308f\u304b\u3063\u305f\u3002\u305d\u306e\u7d50\u679c\u3001\u305d\u306e\u5727\u7c89\u4f53\u306f\u5ba4\u6e29\u3067\u5f93\u6765\u306e\u56fa\u4f53\u5408\u6210\u8a66\u6599\u306e20\u500d\u306b\u3042\u305f\u308b\u30a4\u30aa\u30f3\u4f1d\u5c0e\u5ea6 (2.1\u00d710-5 S cm-1) \u3092\u793a\u3057\u305f\u3002\u307e\u305f\u3001SEM\u89b3\u5bdf\u304a\u3088\u3073\u7de9\u548c\u6642\u9593\u5206\u5e03\u89e3\u6790\u306e\u7d50\u679c\u3001\u7c92\u5b50\u9593\u306e\u30cd\u30c3\u30ad\u30f3\u30b0\u304c\u5927\u304d\u3044\u7dfb\u5bc6\u306a\u5727\u7c89\u4f53\u306f\u5168\u62b5\u6297\u5024\u306b\u5bfe\u3059\u308b\u7c92\u754c\u62b5\u6297\u306e\u5bc4\u4e0e\u304c\u5c11\u306a\u304f\uff087.5%\uff09\u3001\u305d\u306e\u5727\u7c89\u4f53\u3092\u4f7f\u7528\u3057\u305fLi\u91d1\u5c5e\u5bfe\u79f0\u30bb\u30eb\u306f\u3001\u9ad8\u96fb\u6d41\u5bc6\u5ea6 (0.1 mA cm-2) \u306770\u30b5\u30a4\u30af\u30eb\u306e\u9593\u3001\u77ed\u7d61\u3084\u904e\u96fb\u5727\u4e0a\u6607\u306e\u306a\u3044\u826f\u597d\u306a\u30b5\u30a4\u30af\u30eb\u6027\u80fd\u3092\u793a\u3057\u305f\u3002(\u62c5\u5f53: \u8c37\u7aef)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-1802\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2022\/10\/\u56f31.gif\" alt=\"\" width=\"500\" height=\"273\" \/><\/p>\n<p><strong>\u2605\u4f8b\u3000\u9ad8\u3044\u5909\u5f62\u80fd\u3068Li\u62e1\u6563\u6027\u3092\u4f75\u305b\u6301\u3064\u6e96\u5b89\u5b9a\u30b9\u30d4\u30cd\u30eb\u5869\u5316\u7269\u96fb\u6975\u6750\u6599\u306e\u5408\u6210\u3068\u7279\u6027\u8a55\u4fa1 (\u53c2\u8003\u6587\u732e <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/aesr.202000025\">2020<\/a>)<\/strong><\/p>\n<p>\u672c\u7814\u7a76\u3067\u306f\u3001\u9ad8\u30a8\u30cd\u30eb\u30ae\u30fc\u5bc6\u5ea6\u306e\u975e\u713c\u7d50\u30d0\u30eb\u30af\u578b\u5168\u56fa\u4f53\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306e\u305f\u3081\u306b\u3001\u9ad8\u3044\u5909\u5f62\u80fd\u3068Li\u62e1\u6563\u6027\u3092\u6709\u3059\u308b\u7acb\u65b9\u6676Li2FeCl4\u96fb\u6975\u6750\u3092\u63d0\u6848\u3057\u305f\u3002\u4ea4\u6d41\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u6e2c\u5b9a\u3068\u7de9\u548c\u6642\u9593\u5206\u5e03\u89e3\u6790\u304b\u3089\u672c\u6750\u6599\u306f\u5727\u7c89\u306e\u307f\u306b\u3088\u3063\u3066\u3001\u7c92\u754c\u62b5\u6297\u5272\u5408\u304c\u7d043\uff05\u3068\u307b\u3068\u3093\u3069\u306a\u304f\u306a\u3063\u3066\u3044\u308b\u3053\u3068\u304c\u308f\u304b\u3063\u305f \u3002\u307e\u305f\u3001\u5f93\u6765\u306e\u9178\u5316\u7269\u3084\u786b\u5316\u7269\u306e\u96fb\u6975\u6750\u6599\u306e\u5316\u5b66\u62e1\u6563\u4fc2\u6570\u3068\u6bd4\u8f03\u3057\u3066\u3001\u6570\u6841\u9ad8\u3044\u5c0e\u96fb\u7387\u62e1\u6563\u4fc2\u6570 (2.8\u00d710\u221210 cm2 s-1) \u3092\u793a\u3057\u305f\u3002\u62e1\u6563\u7d4c\u8def\u89e3\u6790\u304b\u3089\u3001\u30e1\u30ab\u30ce\u30b1\u30df\u30ab\u30eb\u6cd5\u306b\u3088\u308a\u5e38\u6e29\u51cd\u7d50\u3055\u308c\u305f\u9ad8\u6e29\u76f8\u306b\u304a\u3044\u3066\u3001\u62e1\u6563\u7d4c\u8def\u4e2d\u306eLi\u30a4\u30aa\u30f3\u304c\u975e\u5c40\u5728\u5316\u3057\u9ad8\u3044Li\u62e1\u6563\u6027\u3092\u5b9f\u73fe\u3059\u308b\u3053\u3068\u304c\u793a\u5506\u3055\u308c\u305f\u3002\u3053\u306e\u6750\u6599\u306b\u96fb\u5b50\u4f1d\u5c0e\u6027\u6dfb\u52a0\u7269\u306e\u307f\u3092\u52a0\u3048\u305f\u96fb\u89e3\u8cea\u7121\u6dfb\u52a0\u96fb\u6975\u306f\u300130\u2103\u306b\u304a\u3044\u3066\u9ad8\u3044\u52d5\u4f5c\u96fb\u5727 (3.6 V vs Li\/Li+) \u3067\u5927\u304d\u306a\u904e\u96fb\u4f4d\u304c\u306a\u304f\u30011\u96fb\u5b50\u5145\u96fb\u53cd\u5fdc (\u5bb9\u91cf 126mAh g-1) \u3092\u793a\u3057\u305f\u3002(\u62c5\u5f53: \u8c37\u7aef)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter  wp-image-1803\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2022\/10\/\u56f32.png\" alt=\"\" width=\"364\" height=\"342\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2022\/10\/\u56f32.png 709w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2022\/10\/\u56f32-300x282.png 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2022\/10\/\u56f32-319x300.png 319w\" sizes=\"auto, (max-width: 364px) 100vw, 364px\" \/><\/p>\n<p><strong>\u2605\u4f8b\u3000\u5869\u5316\u7269\u96fb\u89e3\u8cea\u3092\u7528\u3044\u305f3.5 V\u7d1a\u5168\u56fa\u4f53\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u3078\u306eHSAB\u8a2d\u8a08\u539f\u7406\u306e\u9069\u7528 (\u53c2\u8003\u6587\u732e <a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2022\/ta\/d2ta05152d\">2022<\/a>)<\/strong><\/p>\n<p>\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306e\u7279\u9577\u3067\u3042\u308b\u9ad8\u96fb\u4f4d\u4f5c\u52d5\u3092\u6709\u3059\u308b\u5168\u56fa\u4f53\u96fb\u6c60\u306e\u305f\u3081\u306b\u3001\u9ad8\u96fb\u5727\u52d5\u4f5c\u306b\u8010\u3048\u308b\u56fa\u4f53\u96fb\u89e3\u8cea\u304c\u6c42\u3081\u3089\u308c\u308b\u3002\u672c\u7814\u7a76\u3067\u306f\u3001\u8010\u9178\u5316\u6027\u306e\u9ad8\u3044\u5869\u5316\u7269\u96fb\u89e3\u8cea\u3068\u3057\u3066LiAlCl4\u3092\u7528\u3044\u30013.5 V\u7d1a\u96fb\u6975\u3092\u7528\u3044\u305f\u5168\u56fa\u4f53\u96fb\u6c60\u306e\u4f5c\u52d5\u3092\u76ee\u6307\u3057\u305f\u3002\u3057\u304b\u3057\u3001\u4e00\u822c\u7684\u306a\u9178\u5316\u7269\u96fb\u6975 \uff08LiFePO4\u7b49\uff09 \u3092\u7528\u3044\u305f\u96fb\u6c60\u306f\u3001\u4f5c\u52d5\u96fb\u4f4d\u304cLiAlCl4\u306e\u9178\u5316\u96fb\u4f4d\u4ee5\u4e0b\u3067\u3042\u308b\u306b\u3082\u304b\u304b\u308f\u3089\u305a\u3001\u4f4e\u5bb9\u91cf\u3092\u793a\u3059\u3053\u3068\u304c\u308f\u304b\u3063\u305f\u3002\u7b2c\u4e00\u539f\u7406\u8a08\u7b97\u306827Al MAS-NMR\u6e2c\u5b9a\u306e\u30c7\u30fc\u30bf\u304b\u3089\u3001\u96fb\u6975\u3068\u96fb\u89e3\u8cea\u306e\u9593\u3067HSAB\uff08Hard and Soft Acid-Base\uff09\u30eb\u30fc\u30eb\u306b\u57fa\u3065\u304f\u9178\u5869\u57fa\u53cd\u5fdc\u304c\u8d77\u3053\u3063\u3066\u3044\u308b\u3053\u3068\u304c\u793a\u5506\u3055\u308c\u305f\u3002\u4e00\u65b9\u3001\u540c\u3058\u5869\u5316\u7269\u96fb\u6975\uff08Li2FeCl4\uff09\u3092\u7d44\u307f\u5408\u308f\u305b\u308b\u3053\u3068\u3067\u3001\u30b3\u30fc\u30c6\u30a3\u30f3\u30b0\u51e6\u7406\u7b49\u306a\u3057\u3067\u3082\u526f\u53cd\u5fdc\u3092\u6291\u5236\u3057\u3001\u5ba4\u6e29\u3067\u9ad8\u3044\u96fb\u5727 (&gt; 3.6 V vs. Li+\/Li\uff09 \u3068\u53ef\u9006\u5bb9\u91cf (\u301c100 mAh g-1\uff09\u304c\u89b3\u5bdf\u3055\u308c\u305f\u3002\u3053\u308c\u3089\u306e\u7d50\u679c\u306f\u3001\u96fb\u6975\u30fb\u96fb\u89e3\u8cea\u6750\u6599\u306e\u7d44\u307f\u5408\u308f\u305b\u3092\u8003\u3048\u308b\u969b\u306b\u3082HSAB\u30eb\u30fc\u30eb\u306b\u57fa\u3065\u304f\u6750\u6599\u8a2d\u8a08\u304c\u6709\u7528\u3067\u3042\u308b\u4e00\u4f8b\u3092\u793a\u3057\u3066\u3044\u308b\u3068\u540c\u6642\u306b\u3001\u5869\u5316\u7269\u96fb\u6975-\u5869\u5316\u7269\u96fb\u89e3\u8cea\u306e\u7d44\u307f\u5408\u308f\u305b\u304c\u9ad8\u30a8\u30cd\u30eb\u30ae\u30fc\u5bc6\u5ea6\u5168\u56fa\u4f53\u96fb\u6c60\u306b\u3064\u306a\u304c\u308b\u53ef\u80fd\u6027\u3092\u793a\u3057\u3066\u3044\u308b\u3002(\u62c5\u5f53: \u8c37\u7aef)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter  wp-image-1804\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2022\/10\/\u56f33.png\" alt=\"\" width=\"394\" height=\"279\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2022\/10\/\u56f33.png 787w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2022\/10\/\u56f33-300x212.png 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2022\/10\/\u56f33-768x543.png 768w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2022\/10\/\u56f33-425x300.png 425w\" sizes=\"auto, (max-width: 394px) 100vw, 394px\" \/><\/p>\n<div>\n<div><strong>\u2605\u4f8b\u3000\u5168\u56fa\u4f53Na\u96fb\u6c60\u306e\u305f\u3081\u306e\u9ad8Na\u62e1\u6563\u5408\u91d1\u306e\u958b\u767a \uff08\u53c2\u8003\u6587\u732e<a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2023\/ta\/d3ta02787b\">2023<\/a>\uff09<\/strong><\/div>\n<div>\n<div><\/div>\n<div>\n<div>\u5168\u56fa\u4f53Na\u96fb\u6c60\u306f\u74b0\u5883\u306b\u512a\u3057\u3044\u30de\u30a4\u30af\u30ed\u30b0\u30ea\u30c3\u30c9\u3084\u81ea\u52d5\u8eca\u306e\u30a8\u30cd\u30eb\u30ae\u30fc\u8caf\u8535\u30c7\u30a3\u30d0\u30a4\u30b9\u306e\u6709\u671b\u306a\u5019\u88dc\u3067\u3042\u308a\u3001Na\u62e1\u6563\u6027\u306f\u305d\u306e\u6027\u80fd\u306b\u3068\u3063\u3066\u91cd\u8981\u306a\u30d1\u30e9\u30e1\u30fc\u30bf\u3067\u3042\u308b\u3002\u672c\u7814\u7a76\u3067\u306f\u6e96\u5b89\u5b9a\u76f8Na10Sn4\u304c\u3001\u4ed6\u306e\u5408\u91d1\u3084\u9178\u5316\u7269\u30fb\u786b\u5316\u7269\u3088\u308a\u3082\u901f\u3044Na\u62e1\u6563\u4fc2\u6570 (D25 = 5.4 \u00d7 10-7 cm2 s-1) \u3092\u793a\u3059\u3053\u3068\u3092\u898b\u3044\u3060\u3057\u305f\u3002\u307e\u305f\u3001\u3053\u306e\u5408\u91d1\u96fb\u6975\u3092\u7528\u3044\u305f\u5168\u56fa\u4f53Na\u96fb\u6c60\u306b\u304a\u3051\u308b\u754c\u9762\u62b5\u6297\u3082\u3001\u4ed6\u306e\u91d1\u5c5e\u30a2\u30ce\u30fc\u30c9\u3068\u56fa\u4f53\u96fb\u89e3\u8cea\u307e\u305f\u306f\u6db2\u4f53\u96fb\u89e3\u8cea\u3068\u306e\u9593\u3067\u5831\u544a\u3055\u308c\u3066\u3044\u308b\u5024\u3088\u308a\u3082\u5c0f\u3055\u304f (100.1\u03a9cm2)\u3001\u5f93\u6765\u306e\u5168\u56fa\u4f53Na\u96fb\u6c60\u3088\u308a\u3082\u4f4e\u3044\u30a8\u30cd\u30eb\u30ae\u30fc\u30ed\u30b9\u3092\u793a\u3057\u305f\u3002(\u62c5\u5f53: \u8c37\u7aef)<\/div>\n<div><img decoding=\"async\" class=\"aligncenter\" src=\"https:\/\/pubs.rsc.org\/en\/Image\/Get?imageInfo.ImageType=GA&amp;imageInfo.ImageIdentifier.ManuscriptID=D3TA02787B&amp;imageInfo.ImageIdentifier.Year=2023\" alt=\"Graphical abstract: Fast Na-diffusive tin alloy for all-solid-state Na-based batteries\" \/><\/div>\n<\/div>\n<div>\n<p><strong>\u2605<\/strong><strong>\u4f8b\u3000\u5168\u56fa\u4f53<\/strong><strong>Na<\/strong><strong>\u96fb\u6c60\u306e\u305f\u3081\u306e\u30e6\u30d3\u30ad\u30bf\u30b9\u5143\u7d20\u304b\u3089\u306a\u308b\u5869\u5316\u7269\u96fb\u6975\u306e\u958b\u767a<\/strong> <strong>\uff08\u53c2\u8003\u6587\u732e<\/strong><a href=\"https:\/\/rdcu.be\/dxyk4\"><strong>2024<\/strong><\/a><strong>\uff09<\/strong><\/p>\n<p>\u672c\u7814\u7a76\u3067\u306f\u9ad8\u30a8\u30cd\u30eb\u30ae\u30fc\u5bc6\u5ea6\u3092\u6709\u3059\u308b\u5b89\u4fa1\u3067\u5b89\u5168\u306a\u30a8\u30cd\u30eb\u30ae\u30fc\u8caf\u8535\u96fb\u6c60\u3092\u76ee\u6307\u3057\u3001\u69cb\u9020\u30c7\u30fc\u30bf\u30d9\u30fc\u30b9\u306b\u53ce\u9332\u3055\u308c\u3066\u3044\u308b\u5316\u5408\u7269\u306e\u4e2d\u304b\u3089\u3001\u30e6\u30d3\u30ad\u30bf\u30b9\u5143\u7d20\u3067\u69cb\u6210\u3055\u308c\u308bNaFeCl<sub>4<\/sub>\u3092\u96fb\u6975\u6750\u6599\u3068\u3057\u3066\u6ce8\u76ee\u3057\u305f\u3002NaFeCl<sub>4<\/sub>\u96fb\u6975\u306f\u3001\u5869\u7d20\u306e\u9ad8\u3044\u96fb\u6c17\u9670\u6027\u5ea6\u7531\u6765\u3068\u601d\u308f\u308c\u308b\u9ad8\u3044\u4f5c\u52d5\u96fb\u4f4d\uff08~3.45 V vs Na\/Na<sup>+<\/sup>\u3001\u540c\u3058Fe<sup>2+\/3+<\/sup>\u30ec\u30c9\u30c3\u30af\u30b9\u306e\u9178\u5316\u7269\u96fb\u6975\u3067\u306f~1.5 V vs Na\/Na<sup>+<\/sup>\uff09\u3092\u793a\u3057\u3001\u5831\u544a\u3055\u308c\u3066\u3044\u308b\u5168\u56fa\u4f53Na\u96fb\u6c60\u3068\u6bd4\u8f03\u3057\u3066\u9ad8\u3044\u30a8\u30cd\u30eb\u30ae\u30fc\u5bc6\u5ea6 (281Wh (kg-cathode)<sup>-1<\/sup>) \u3092\u9054\u6210\u3057\u3066\u3044\u308b\u3002(\u62c5\u5f53: \u8c37\u7aef)<\/p>\n<\/div>\n<div>\n<div><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter  wp-image-1928\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2024\/02\/\u753b\u50cf1.png\" alt=\"\" width=\"344\" height=\"240\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2024\/02\/\u753b\u50cf1.png 449w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2024\/02\/\u753b\u50cf1-300x209.png 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2024\/02\/\u753b\u50cf1-430x300.png 430w\" sizes=\"auto, (max-width: 344px) 100vw, 344px\" \/><\/div>\n<\/div>\n<\/div>\n<div><\/div>\n<div><strong>\u2605<\/strong><strong>\u4f8b\u3000\u5168\u56fa\u4f53\u96fb\u6c60\u6750\u6599\u306b\u304a\u3044\u3066\u91cd\u8981\u306a\u5909\u5f62\u80fd\u306b\u95a2\u3059\u308b\u6709\u7528\u306a\u8a2d\u8a08\u30d1\u30e9\u30e1\u30fc\u30bf\u304a\u3088\u3073\u6750\u6599\u30b9\u30af\u30ea\u30fc\u30cb\u30f3\u30b0\u6307\u6a19\u306e\u63d0\u6848<\/strong><strong>\uff08\u53c2\u8003\u6587\u732e<\/strong><a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2024\/ta\/d4ta02328e\"><strong>2024<\/strong><\/a><strong>\uff09<\/strong><\/div>\n<\/div>\n<div>\n<p>\u5168\u56fa\u4f53\u96fb\u6c60\u6750\u6599\u306b\u306f\u9ad8Li\u4f1d\u5c0e\u6027\u306b\u52a0\u3048\u3066\u3001\u7c92\u5b50\u9593\u306e\u63a5\u89e6\u306e\u305f\u3081\u306b\u9ad8\u3044\u5909\u5f62\u80fd (\u5727\u7c89\u6642\u306e\u9ad8\u3044\u76f8\u5bfe\u5bc6\u5ea6\u3084\u4f4e\u3044\u7c92\u5b50\u9593\u62b5\u6297) \u304c\u6c42\u3081\u3089\u308c\u307e\u3059\u3002\u4f1d\u5c0e\u6027\u306b\u95a2\u3057\u3066\u306f\u3053\u308c\u307e\u3067\u6750\u6599\u30b9\u30af\u30ea\u30fc\u30cb\u30f3\u30b0\u624b\u6cd5\u304c\u5831\u544a\u3055\u308c\u3066\u3044\u307e\u3057\u305f\u304c\u3001\u672c\u7814\u7a76\u3067\u306f\u525b\u6027\u7387\u304c\u5909\u5f62\u80fd\u306e\u8a2d\u8a08\u30d1\u30e9\u30e1\u30fc\u30bf\u3068\u306a\u308a\u3001\u305d\u308c\u306b\u3088\u3063\u3066\u52b9\u7387\u7684\u306b\u6750\u6599\u30b9\u30af\u30ea\u30fc\u30cb\u30f3\u30b0\u3067\u304d\u308b\u3053\u3068\u3092\u793a\u3057\u307e\u3057\u305f\u3002(\u62c5\u5f53: \u8c37\u7aef)<\/p>\n<\/div>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter  wp-image-1983\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2024\/06\/\u753b\u50cf1.png\" alt=\"\" width=\"409\" height=\"415\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2024\/06\/\u753b\u50cf1.png 737w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2024\/06\/\u753b\u50cf1-295x300.png 295w\" sizes=\"auto, (max-width: 409px) 100vw, 409px\" \/><\/p>\n<p><strong>\u2605\u4f8b\u3000\u5869\u5316\u7269\u96fb\u6975\u306e\u30ec\u30c9\u30c3\u30af\u30b9\u6e96\u4f4d\u8a2d\u8a08\u306b\u3088\u308a \u9244\u7cfb\u5168\u56fa\u4f53\u96fb\u6c60\u3067\u4e16\u754c\u6700\u9ad8\u6c34\u6e96\u306e\u6027\u80fd\u3092\u9054\u6210 (\u53c2\u8003\u6587\u732e<a href=\"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/aenm.202504110?af=R\">2025<\/a>)<\/strong><\/p>\n<p>\u672c\u7814\u7a76\u3067\u306f\u3001\u6b21\u4e16\u4ee3\u306e\u9ad8\u6027\u80fd\u96fb\u6c60\u3067\u3042\u308b\u5168\u56fa\u4f53\u96fb\u6c60\u306e\u958b\u767a\u306b\u5411\u3051\u3001\u5f93\u6765\u4e3b\u6d41\u306e\u9178\u5316\u7269\u3067\u306f\u306a\u304f\u5869\u5316\u7269\u96fb\u6975\u306b\u7740\u76ee\u3057\u305f\u3002\u5869\u5316\u7269\u96fb\u6975\u306f\u9ad8\u96fb\u5727\u3067\u4f5c\u52d5\u3067\u304d\u308b\u5229\u70b9\u304c\u3042\u308b\u4e00\u65b9\u3001\u904e\u5145\u96fb\u306b\u3088\u3063\u3066\u5869\u7d20\u30ac\u30b9\u304c\u767a\u751f\u3059\u308b\uff08\u5869\u7d20\u8131\u96e2\uff09\u3068\u3044\u3046\u8ab2\u984c\u3092\u62b1\u3048\u3066\u3044\u308b\u3002\u305d\u3053\u3067\u30013d\u9077\u79fb\u91d1\u5c5e\u5869\u5316\u7269\u306e\u96fb\u5b50\u72b6\u614b\u3092\u4f53\u7cfb\u7684\u306b\u6574\u7406\u3057\u3001\u4f5c\u52d5\u96fb\u4f4d\u3068\u5869\u7d20\u8131\u96e2\u306e\u95a2\u4fc2\u3092\u8aac\u660e\u3067\u304d\u308b\u300c\u30ec\u30c9\u30c3\u30af\u30b9\u6e96\u4f4d\u30e2\u30c7\u30eb\u300d\u3092\u69cb\u7bc9\u3057\u305f\u3002\u3055\u3089\u306b\u3001\u9244\u5869\u5316\u7269\uff08Li\u2082FeCl\u2084\uff09\u306e\u4e00\u90e8\u306e\u5869\u7d20\u3092\u9178\u7d20\u306b\u7f6e\u63db\u3059\u308b\u3053\u3068\u3067\u3001\u30ec\u30c9\u30c3\u30af\u30b9\u6e96\u4f4d\u3092\u30c1\u30e5\u30fc\u30cb\u30f3\u30b0\u3057\u3001\u5869\u7d20\u8131\u96e2\u3092\u6291\u3048\u306a\u304c\u3089\u5bb9\u91cf\u306e\u5411\u4e0a\u3092\u5b9f\u73fe\u3057\u305f\u3002\u305d\u306e\u7d50\u679c\u3001\u8cc7\u6e90\u7684\u306b\u8c4a\u5bcc\u3067\u5b89\u4fa1\u306a\u9244\u3092\u6d3b\u7528\u3057\u305f\u5168\u56fa\u4f53\u96fb\u6c60\u306b\u304a\u3044\u3066\u3001\u4e16\u754c\u6700\u9ad8\u6c34\u6e96\u3068\u306a\u308b\u30a8\u30cd\u30eb\u30ae\u30fc\u5bc6\u5ea6\uff08330 Wh\/kg-cathode\uff09\u306e\u9054\u6210\u306b\u6210\u529f\u3057\u305f\u3002(\u62c5\u5f53: \u8c37\u7aef)<\/p>\n\n\t\t<style type=\"text\/css\">\n\t\t\t#gallery-1 {\n\t\t\t\tmargin: auto;\n\t\t\t}\n\t\t\t#gallery-1 .gallery-item {\n\t\t\t\tfloat: left;\n\t\t\t\tmargin-top: 10px;\n\t\t\t\ttext-align: center;\n\t\t\t\twidth: 100%;\n\t\t\t}\n\t\t\t#gallery-1 img {\n\t\t\t\tborder: 2px solid #cfcfcf;\n\t\t\t}\n\t\t\t#gallery-1 .gallery-caption {\n\t\t\t\tmargin-left: 0;\n\t\t\t}\n\t\t\t\/* see gallery_shortcode() in wp-includes\/media.php *\/\n\t\t<\/style>\n\t\t<div id='gallery-1' class='gallery galleryid-58 gallery-columns-1 gallery-size-medium'><dl class='gallery-item'>\n\t\t\t<dt class='gallery-icon landscape'>\n\t\t\t\t<a href='http:\/\/nakayama.web.nitech.ac.jp\/jp\/%e7%a0%94%e7%a9%b6%e6%b4%bb%e5%8b%95\/%e5%ae%9f%e9%a8%93%e7%b3%bb%e7%a0%94%e7%a9%b6-2\/%e7%94%bb%e5%83%8f1-3\/'><img loading=\"lazy\" decoding=\"async\" width=\"300\" height=\"268\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2025\/09\/\u753b\u50cf1-300x268.png\" class=\"attachment-medium size-medium\" alt=\"\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2025\/09\/\u753b\u50cf1-300x268.png 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2025\/09\/\u753b\u50cf1.png 317w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a>\n\t\t\t<\/dt><\/dl><br style=\"clear: both\" \/>\n\t\t<\/div>\n\n<h6><strong><a name=\"a01\"><\/a>\u96fb\u6975\u53cd\u5fdc\u306e\u7d20\u904e\u7a0b\u89e3\u6790<\/strong><\/h6>\n<p style=\"text-align: left;\">\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306e\u96fb\u6975\uff08\u30bb\u30e9\u30df\u30c3\u30af\u30b9\u6750\u6599\uff09\u3068\u96fb\u89e3\u8cea\uff08\u6709\u6a5f\u96fb\u89e3\u6db2\uff09\u306e\u9593\uff08\u754c\u9762\uff09\u3067\u306f\u3001\u5145\u653e\u96fb\u4e2d\u306b\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u306e\u4ea4\u63db\u53cd\u5fdc\u304c\u884c\u308f\u308c\u3066\u3044\u308b\u3002\u308f\u308c\u308f\u308c\u306f\u3001\u3053\u306e\u754c\u9762\u3067\u306e\u30a4\u30aa\u30f3\u4ea4\u63db\u53cd\u5fdc\u6a5f\u69cb\u3092\u539f\u5b50\u30b9\u30b1\u30fc\u30eb\u3067\u7406\u89e3\u3059\u308b\u3053\u3068\u3092\u6a21\u7d22\u3057\u3066\u3044\u308b\u3002<\/p>\n<p style=\"text-align: left;\">\u3053\u306e\u3088\u3046\u306a\u7814\u7a76\u3067\u5f97\u3089\u308c\u305f\u6210\u679c\u306f\u3001\u4ea4\u63db\u53cd\u5fdc\u306b\u3088\u308b\u5185\u90e8\u62b5\u6297\uff08\u754c\u9762\u62b5\u6297\uff09\u3092\u4f4e\u4e0b\u3055\u305b\u3066\u9ad8\u51fa\u529b\u5316\uff08\u9ad8\u901f\u5145\u653e\u96fb\u3067\u304d\u308b\u80fd\u529b\uff09\u3059\u308b\u6280\u8853\u3092\u78ba\u7acb\u3059\u308b\u3053\u3068\u306b\u8ca2\u732e\u3059\u308b\u3068\u8003\u3048\u3066\u3044\u308b\u3002<\/p>\n<p style=\"text-align: left;\"><b>\u2605<\/b><b>\u4f8b\u3000AC\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u6cd5\u306b\u3088\u308b\u30a2\u30c9\u30a2\u30c8\u30e0(adatom)\u7406\u8ad6\u306e\u691c\u8a3c \uff08\u53c2\u8003\u6587\u732e <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jp036059k\">2003<\/a>\uff09<\/b><\/p>\n<p style=\"text-align: left;\"><b><\/b>\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306e\u96fb\u6975\u53cd\u5fdc\u3067\u306f\u3001Bruce\u3089\u304c\u63d0\u6848\u3057\u305fadatom\u30e2\u30c7\u30eb\uff08P. G. Bruce et. al., J. Electroanal. Chem., 322, 93 (1992)\uff09\u3067\u8aac\u660e\u3067\u304d\u308b\u3053\u3068\u3092AC\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u6e2c\u5b9a\u306b\u3088\u308a\u660e\u3089\u304b\u306b\u3057\u305f\u3002\u5177\u4f53\u7684\u306b\u306f\u3001\u96fb\u6975\u53cd\u5fdc\u3067\u306f\u2460\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u306e\u8131\u6eb6\u5a92\u548c\u3068\u2463\u96fb\u6975\u8868\u9762\u30a4\u30f3\u30bf\u30fc\u30ab\u30ec\u30fc\u30b7\u30e7\u30f3\u306e\u4e8c\u3064\u306e\u304c\u4e3b\u305f\u308b\u754c\u9762\u62b5\u6297\u306b\u306a\u308b\u3053\u3068\u3092\u78ba\u8a8d\u3057\u305f\u3002<br \/>\n\u3053\u308c\u307e\u3067\u3001\u5747\u4e00\u7cfb\u306e\u96fb\u6c17\u5316\u5b66\u53cd\u5fdc\u306b\u304a\u3051\u308b\u96fb\u8377\u79fb\u52d5\u53cd\u5fdc\u306f\u3001\u96fb\u6975\u304b\u3089\u6eb6\u6db2\u4e2d\uff08\u96fb\u6c17\u4e8c\u91cd\u5c64\uff09\u306e\u30a4\u30aa\u30f3\u306b\u96fb\u5b50\u304c\u98db\u3073\u79fb\u308b\u904e\u7a0b\uff08\u96fb\u8377\u79fb\u52d5\u30fb\u96fb\u5b50\u79fb\u52d5\uff09\u304c\u7d20\u904e\u7a0b\u3067\u3042\u308b\u3068\u3057\u3066\u3001Butler-Volmer\u5f0f\u304c\u63d0\u6848\u3055\u308c\u3066\u304d\u305f\u3002\u3057\u304b\u3057\u3001\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306e\u5834\u5408\u3001\u96fb\u5b50\u79fb\u52d5\u306f\u96fb\u6975\u56fa\u4f53\u5185\u3067\u5b8c\u7d50\u3059\u308b\uff08\u96fb\u6975\u5185\u306e\u9077\u79fb\u91d1\u5c5e\u3092\u9178\u5316\u9084\u5143\u3059\u308b\uff09\u305f\u3081\u3001\u5747\u4e00\u7cfb\u96fb\u6975\u53cd\u5fdc\u306b\u6bd4\u3079\u3066\u5c0f\u3055\u3044\u3068\u8003\u3048\u3089\u308c\u308b\u3002\u305d\u3053\u3067\u6eb6\u5a92\u7a2e\u3092\u5909\u66f4\u3057\u305f\u308a\u3001\u6e29\u5ea6\u3092\u5236\u5fa1\u3057\u305f\u6761\u4ef6\u4e0b\u3067AC\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u3092\u6e2c\u5b9a\u3057\u305f\u7d50\u679c\u3001\u96fb\u6975\u53cd\u5fdc\u306e\u5f8b\u901f\u904e\u7a0b\u304c\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u306e\u8131\u6eb6\u5a92\u548c\u3068\u96fb\u6975\u8868\u9762\u306e\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u304c\u5185\u90e8\u306b\u30a4\u30f3\u30bf\u30fc\u30ab\u30ec\u30fc\u30b7\u30e7\u30f3\u3057\u3066\u3044\u304f\u904e\u7a0b\u3067\u3042\u308b\u3053\u3068\u3092\u898b\u51fa\u3057\u305f\u3002<img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-308 size-full\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/AdAtom.png\" sizes=\"auto, (max-width: 447px) 100vw, 447px\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/AdAtom-300x177.png 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/AdAtom.png 447w\" alt=\"AdAtom\" width=\"447\" height=\"264\" \/><\/p>\n<p style=\"text-align: left;\"><b>\u2605<\/b><b>\u4f8b\u3000<\/b><b>AC\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u6cd5\u3068\u7b2c\u4e00\u539f\u7406\u8a08\u7b97\u306b\u3088\u308b\u30a2\u30c9\u30a2\u30c8\u30e0(adatom)\u7406\u8ad6\u306e\u691c\u8a3c\uff12 \uff08\u53c2\u8003\u6587\u732e <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jp509232m\">2014<\/a>\uff09<\/b><\/p>\n<p style=\"text-align: left;\">\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306e\u96fb\u6975\u53cd\u5fdc\u306e\u7d20\u904e\u7a0b\u3068\u3057\u3066\u3001(1) \u8131\u6eb6\u5a92\u548c\u3068 (2) Lattice Incorporation(\u683c\u5b50\u5185\u633f\u5165)\u306e\uff12\u3064\u306e\u904e\u7a0b\u304c\u95a2\u4e0e\u3059\u308b\u3053\u3068\u3092\u4e0a\u8a18\u306e\u7814\u7a76\u4f8b\u3067\u63d0\u6848\u3057\u305f\u304c\u3001\u7269\u7406\u7684\u306a\u30a4\u30e1\u30fc\u30b8\u304c\u660e\u78ba\u306a\u8131\u6eb6\u5a92\u548c\u904e\u7a0b\u306b\u6bd4\u3079\u3066\u3001Lattice incorporation\u904e\u7a0b\u306f\u30a4\u30e1\u30fc\u30b8\u304c\u66d6\u6627\u3067\u3042\u308a\u3001\u6750\u6599\u8a2d\u8a08\u4e0a\u306e\u8ab2\u984c\u3067\u3042\u308b\u3002<\/p>\n<p style=\"text-align: left;\">\u305d\u3053\u3067\u3001\u7b2c\u4e00\u539f\u7406\u8a08\u7b97\u306b\u3088\u308b\u8868\u9762\u30ea\u30c1\u30a6\u30e0\u8131\u633f\u5165\u8a08\u7b97\u306e\u7d50\u679c\u3068\u3001\u96fb\u4f4d\u5236\u5fa1\u3057\u305fAC\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u6e2c\u5b9a\u3092\u99c6\u4f7f\u3059\u308b\u3053\u3068\u3067\u3001Lattice incorporation\u904e\u7a0b\u304c\u8868\u9762\u306b\u304a\u3051\u308b\u30ea\u30c1\u30a6\u30e0\u306e\u6b20\u9665\u751f\u6210\u30a8\u30cd\u30eb\u30ae\u30fc\u304c\u30d0\u30eb\u30af\u306e\u751f\u6210\u30a8\u30cd\u30eb\u30ae\u30fc\u306b\u6bd4\u3079\u3066\u5927\u304d\u304f\u5909\u5316\u3057\u3066\u3044\u308b\u3053\u3068\u306b\u3088\u308a\u3001\u30dd\u30c6\u30f3\u30b7\u30e3\u30eb\u969c\u58c1\u304c\u767a\u751f\u3057\u3066\u3044\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3057\u305f\u3002\u3053\u306e\u30e2\u30c7\u30eb\u3067\u306f\u3001\u5f93\u6765\uff12\u6b21\u5143\u7684\u306a\u5e73\u9762\u3068\u3057\u3066\u6271\u3063\u3066\u304d\u305f\u96fb\u6975\u8868\u9762\u306e\u30a4\u30e1\u30fc\u30b8\u3068\u306f\u7570\u306a\u308a\u3001\u30ca\u30ce\u30e1\u30fc\u30c8\u30eb\u30b9\u30b1\u30fc\u30eb\u306e\u539a\u307f\u3092\u6709\u3059\u308b\u8868\u9762\u76f8\u306e\u5b58\u5728\u3092\u60f3\u5b9a\u3057\u3066\u3044\u308b\u3002\u3053\u306e\u3088\u3046\u306a\u8003\u3048\u65b9\u306b\u57fa\u3065\u3051\u3070\u3001\u30ca\u30ce\u7c92\u5b50\u6b63\u6975\u6750\u6599\u3067\u96fb\u4f4d\u66f2\u7dda\u304c\u5909\u5316\u3059\u308b\u3053\u3068\u306a\u3069\u3092\u8aac\u660e\u3059\u308b\u3053\u3068\u3082\u53ef\u80fd\u3067\u3042\u308b\u3002<\/p>\n<p style=\"text-align: left;\"><b><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-335 alignnone\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LatticeIncorporation2014-2.jpg\" alt=\"LatticeIncorporation2014\" width=\"447\" height=\"287\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LatticeIncorporation2014-2.jpg 447w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LatticeIncorporation2014-2-300x193.jpg 300w\" sizes=\"auto, (max-width: 447px) 100vw, 447px\" \/><\/b><\/p>\n<p style=\"text-align: left;\"><b>\u2605\u4f8b\u3000<b>AC\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u6cd5\u306b\u3088\u308b\u5408\u91d1\u7cfb\u8ca0\u6975\u306e\u53cd\u5fdc\u6a5f\u69cb\u691c\u8a3c \uff08\u53c2\u8003\u6587\u732e <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jp036059k\">2003<\/a>\uff09<br \/>\n<\/b><\/b>\u5408\u91d1\u7cfb\u8ca0\u6975Cu2Sb\u306e\u30ea\u30c1\u30a6\u30e0\u633f\u5165\u53cd\u5fdc\u306b\u3064\u3044\u3066\u3001\u305d\u306e\u53cd\u5fdc\u901f\u5ea6\u8ad6\u3092AC\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u6cd5\u3068\u71b1\u6e2c\u5b9a\u306b\u3088\u3063\u3066\u691c\u8a3c\u3092\u884c\u3063\u305f\u3002\u305d\u306e\u7d50\u679c\u3001\u53cd\u5fdc\u521d\u671f\u306e\u4e8c\u76f8\u5171\u5b58\u53cd\u5fdc\u3067\u306f\u3001\u6838\u751f\u6210\u3068\u6210\u9577\u904e\u7a0b\u304c\u5f8b\u901f\u3068\u306a\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3067\u304d\u305f\u3002\u3053\u306e\u7814\u7a76\u6210\u679c\u306f\u3001\u5408\u91d1\u8ca0\u6975\u306b\u7279\u6709\u306a\u521d\u671f\u4e0d\u53ef\u9006\u53cd\u5fdc\u306e\u30e1\u30ab\u30cb\u30ba\u30e0\u89e3\u660e\u306b\u8ca2\u732e\u3059\u308b\u3068\u3068\u3082\u306b\u3001\u4e8c\u76f8\u5171\u5b58\u53cd\u5fdc\u306b\u304a\u3051\u308b\u53cd\u5fdc\u30c0\u30a4\u30ca\u30df\u30af\u30b9\u3092\u6838\u751f\u6210\u30fb\u6210\u9577\u904e\u7a0b\u306e\u89b3\u70b9\u304b\u3089\u8aac\u660e\u3059\u308b\u30e2\u30c7\u30eb\u3092\u63d0\u4f9b\u3059\u308b\u3053\u3068\u306b\u3064\u306a\u304c\u308b\u3068\u8003\u3048\u3066\u3044\u308b\u3002<img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-326 size-full\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Nucleation.png\" sizes=\"auto, (max-width: 678px) 100vw, 678px\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Nucleation-300x169.png 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Nucleation-500x282.png 500w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Nucleation.png 678w\" alt=\"Nucleation\" width=\"678\" height=\"383\" \/><\/p>\n<p style=\"text-align: left;\"><b>\u2605\u4f8b\u3000\u4e8c\u76f8\u5171\u5b58\u53cd\u5fdc\u7cfb\u306b\u304a\u3051\u308b\u6838\u751f\u6210\u30fb\u6210\u9577\u306e\u53cd\u5fdc\u6a5f\u69cb\uff08\u53c2\u8003\u6587\u732e\u3000<a href=\"http:\/\/dx.doi.org\/10.1149\/1.2815477\">2007<\/a>\uff09<br \/>\n<\/b>\u305d\u3053\u3067\u3001\u5408\u91d1\u7cfb\u8ca0\u6975Cu2Sb\u306e\u30ea\u30c1\u30a6\u30e0\u633f\u5165\u53cd\u5fdc\u306b\u3064\u3044\u3066\u3001\u305d\u306e\u53cd\u5fdc\u901f\u5ea6\u8ad6\u3092AC\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u6cd5\u3068\u71b1\u6e2c\u5b9a\u306b\u3088\u3063\u3066\u691c\u8a3c\u3092\u884c\u3063\u305f\u3002\u305d\u306e\u7d50\u679c\u3001\u53cd\u5fdc\u521d\u671f\u306e\u4e8c\u76f8\u5171\u5b58\u53cd\u5fdc\u3067\u306f\u3001\u6838\u751f\u6210\u3068\u6210\u9577\u904e\u7a0b\u304c\u5f8b\u901f\u3068\u306a\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3067\u304d\u305f\u3002\u3053\u306e\u7814\u7a76\u6210\u679c\u306f\u3001\u5408\u91d1\u8ca0\u6975\u306b\u7279\u6709\u306a\u521d\u671f\u4e0d\u53ef\u9006\u53cd\u5fdc\u306e\u30e1\u30ab\u30cb\u30ba\u30e0\u89e3\u660e\u306b\u8ca2\u732e\u3059\u308b\u3068\u3068\u3082\u306b\u3001\u4e8c\u76f8\u5171\u5b58\u53cd\u5fdc\u306b\u304a\u3051\u308b\u53cd\u5fdc\u30c0\u30a4\u30ca\u30df\u30af\u30b9\u3092\u6838\u751f\u6210\u30fb\u6210\u9577\u904e\u7a0b\u306e\u89b3\u70b9\u304b\u3089\u8aac\u660e\u3059\u308b\u30e2\u30c7\u30eb\u3092\u63d0\u4f9b\u3059\u308b\u3053\u3068\u306b\u3064\u306a\u304c\u308b\u3068\u8003\u3048\u3066\u3044\u308b\u3002<\/p>\n<p style=\"text-align: left;\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-309 aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Asym1.jpg\" alt=\"Asym1\" width=\"622\" height=\"285\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Asym1.jpg 622w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Asym1-300x137.jpg 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Asym1-500x229.jpg 500w\" sizes=\"auto, (max-width: 622px) 100vw, 622px\" \/><\/p>\n<div class=\"entry-content\"><\/div>\n<p><strong>\u2605\u4f8b\u3000\u30e9\u30d7\u30e9\u30b9\u5909\u63db\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u6cd5\u306b\u3088\u308b\u5145\u96fb\u3068\u653e\u96fb\u53cd\u5fdc\u306e\u5206\u96e2\uff08\u53c2\u8003\u6587\u732e\u3000<a href=\"http:\/\/link.springer.com\/article\/10.1007\/s10008-016-3465-3\">2016<\/a>\uff09<\/strong><br \/>\n\u5f93\u6765\u306e\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u6cd5\u3067\u306f\u5145\u96fb\u53cd\u5fdc\u3068\u653e\u96fb\u53cd\u5fdc\u3092\u5206\u96e2\u3059\u308b\u3053\u3068\u304c\u51fa\u6765\u306a\u3044\u3002\u305d\u3053\u3067\u76f4\u6d41\u96fb\u6d41\u30d1\u30eb\u30b9\u306e\u96fb\u5727\u5fdc\u7b54\u3092\u30e9\u30d7\u30e9\u30b9\u5909\u63db\u3057\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u30b9\u30da\u30af\u30c8\u30eb\u3092\u5f97\u308b\u65b9\u6cd5\uff08Takano\u3089\u3001J. Electrochem. Soc. 147, 922 (2000)\uff09\u3092\u7528\u3044\u308b\u3053\u3068\u3067\u3001\u5145\u96fb\u3068\u653e\u96fb\u306e\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u3092\u5206\u96e2\u3057\u305f\u3002\u307e\u305f\u3001\u3053\u306e\u65b9\u6cd5\u306b\u3088\u308a\u96fb\u6d41\u5bc6\u5ea6\u306b\u5bfe\u3059\u308b\u904e\u96fb\u5727\u5909\u5316\u3082\u8a08\u6e2c\u3057\u3001\u30d0\u30c8\u30e9\u30fc\u30dc\u30eb\u30de\u30fc\u578b\u306e\u904e\u96fb\u5727\u30d7\u30ed\u30d5\u30a1\u30a4\u30eb\u3092\u5f97\u308b\u3053\u3068\u306b\u6210\u529f\u3057\u305f\u3002\u9ad8\u96fb\u6d41\u5bc6\u5ea6\u4e0b\u3067\u306f\u3001\u5145\u96fb\u3068\u653e\u96fb\u3067\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u30b9\u30da\u30af\u30c8\u30eb\u306b\u5927\u304d\u306a\u5dee\u304c\u898b\u3089\u308c\u308b\u3053\u3068\u3092\u78ba\u8a8d\u3057\u305f\u3002<br \/>\n<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-908\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/laplacet2.jpg\" alt=\"laplacet2\" width=\"907\" height=\"314\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/laplacet2.jpg 907w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/laplacet2-300x104.jpg 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/laplacet2-768x266.jpg 768w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/laplacet2-500x173.jpg 500w\" sizes=\"auto, (max-width: 907px) 100vw, 907px\" \/><\/p>\n<p><strong>\u4f8b\u3000\u30e9\u30d7\u30e9\u30b9\u5909\u63db\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u6cd5\u306b\u3088\u308b\u30ea\u30c1\u30a6\u30e0\u91d1\u5c5e\u96fb\u6975\u306e\u8131\u6eb6\u5a92\u548c\u62b5\u6297\u306e\u89e3\u6790\u3068\u30ea\u30c1\u30a6\u30e0\u30c7\u30f3\u30c9\u30e9\u30a4\u30c8\u6291\u5236 \uff08\u53c2\u8003\u6587\u732e\u3000<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.analchem.9b05321\">2020<\/a>\uff09<\/strong><br \/>\nLi\u96fb\u6975\u306e\u5b9f\u7528\u5316\u3092\u59a8\u3052\u308b\u3001\u4e00\u3064\u306e\u5927\u304d\u306a\u8981\u56e0\u3067\u3042\u308b\u30c7\u30f3\u30c9\u30e9\u30a4\u30c8\u304c\u95a2\u4fc2\u3059\u308b\u8131\u6eb6\u5a92\u548c\u62b5\u6297\u3092Laplace\u5909\u63db\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u6cd5\u306b\u3088\u308a\u6e2c\u5b9a\u3057\u305f\u3002\u305d\u306e\u904e\u7a0b\u3067\u3001\u8131\u6eb6\u5a92\u548c\u62b5\u6297\u3068\u6eb6\u5a92\u548c\u62b5\u6297\u306b\u306f\u975e\u5bfe\u79f0\u6027\u304c\u5b58\u5728\u3059\u308b\u3053\u3068\u3092\u793a\u3057\u3001\u4e00\u822c\u7684\u306b\u5927\u304d\u306a\u30a8\u30cd\u30eb\u30ae\u30fc\u30ed\u30b9\u3092\u751f\u3058\u308b\u3068\u8003\u3048\u3089\u308c\u3066\u3044\u308b\u8131\u6eb6\u5a92\u548c\u62b5\u6297\u3088\u308a\u3001\u6eb6\u5a92\u548c\u62b5\u6297\u306e\u65b9\u304c\u5927\u304d\u306a\u62b5\u6297\u3092\u6709\u3059\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3057\u305f\u3002\u307e\u305f\u3001\u5145\u96fb\u6642\u306e\u307f\u8d77\u3053\u308b\u30c7\u30f3\u30c9\u30e9\u30a4\u30c8\u306f\u3001\u5145\u96fb\u6642\u306e\u8131\u6eb6\u5a92\u548c\u62b5\u6297\u304c\u5927\u304d\u3044\u7a0b\u6291\u5236\u3055\u308c\u308b\u3053\u3068\u3092\u793a\u3057\u305f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-1428 size-medium\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/TOC-\u30b3\u30d4\u30fc-300x225.jpg\" alt=\"TOC - \u30b3\u30d4\u30fc\" width=\"300\" height=\"225\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/TOC-\u30b3\u30d4\u30fc-300x225.jpg 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/TOC-\u30b3\u30d4\u30fc-768x576.jpg 768w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/TOC-\u30b3\u30d4\u30fc-400x300.jpg 400w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/03\/TOC-\u30b3\u30d4\u30fc.jpg 960w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/p>\n<p><strong>\u5168\u56fa\u4f53\u30ea\u30c1\u30a6\u30e0\u30dd\u30ea\u30de\u30fc\u96fb\u6c60\u306e\u958b\u767a<a name=\"a02\"><\/a>\u5168\u56fa\u4f53\u30ea\u30c1\u30a6\u30e0\u30dd\u30ea\u30de\u30fc\u96fb\u6c60\u306e\u958b\u767a<\/strong><\/p>\n<p>\u65e2\u5b58\u306e\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306f\u53ef\u71c3\u6027\u30fb\u81ea\u5df1\u71c3\u713c\u6027\u306e\u6709\u6a5f\u6eb6\u5a92\u3092\u7528\u3044\u3066\u3044\u308b\u305f\u3081\u306b\u5b89\u5168\u6027\u306b\u5bfe\u3059\u308b\u81f4\u547d\u7684\u306a\u4e0d\u5b89\u3092\u62b1\u3048\u3066\u3044\u308b\u3002\u305d\u3053\u3067\u3001\u6709\u6a5f\u96fb\u89e3\u8cea\u3092\u3001\u96e3\u71c3\u6027\u306e\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u5c0e\u96fb\u6027\u30dd\u30ea\u30de\u30fc\u96fb\u89e3\u8cea\u306b\u7f6e\u304d\u63db\u3048\u3001\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u3092\u5168\u56fa\u4f53\u5316\u3059\u308b\u3053\u3068\u3067\u9ad8\u3044\u5b89\u5168\u6027\u304c\u671f\u5f85\u3055\u308c\u308b\u30ea\u30c1\u30a6\u30e0\u30dd\u30ea\u30de\u30fc\u96fb\u6c60\u306e\u958b\u767a\u3092\u5b9f\u65bd\u3057\u3066\u3044\u308b\u3002<br \/>\n\u3053\u306e\u3088\u3046\u306a\u5168\u56fa\u4f53\u30ea\u30c1\u30a6\u30e0\u30dd\u30ea\u30de\u30fc\u96fb\u6c60\u306f\u3001\u66f4\u306b\u30e9\u30df\u30cd\u30fc\u30c8\u6280\u8853\u3092\u4f75\u7528\u3059\u308b\u3053\u3068\u3067\u3001\u30d5\u30ec\u30ad\u30b7\u30d6\u30eb\u30b7\u30fc\u30c8\u5316\u3084\u30b9\u30bf\u30c3\u30af\u5316\u3082\u53ef\u80fd\u3067\u3042\u308a\u3001\u8efd\u91cf\u30fb\u5927\u5bb9\u91cf\u304b\u3064\u653e\u71b1\u7279\u6027\u306b\u512a\u308c\u305f\u96fb\u6c60\u306e\u4f5c\u6210\u304c\u53ef\u80fd\u3067\u3042\u308b\u3068\u8003\u3048\u3089\u308c\u308b\u3002\u3057\u305f\u304c\u3063\u3066\u3001\u3053\u308c\u307e\u3067\u643a\u5e2f\u7528\u9014\u304c\u4e2d\u5fc3\u3067\u3042\u3063\u305f\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u3092\u5927\u578b\u5316\u3059\u308b\u969b\u306b\u3001\u5168\u56fa\u4f53\u30dd\u30ea\u30de\u30fc\u96fb\u6c60\u306f\u6709\u5229\u3067\u3042\u308b\u3068\u8003\u3048\u3066\u3044\u308b\u3002\u5927\u578b\u96fb\u6c60\u306f\u3001\u518d\u751f\u53ef\u80fd\u30a8\u30cd\u30eb\u30ae\u30fc\u3092\u65e2\u5b58\u96fb\u529b\u7db2\u3067\u6d3b\u7528\u3055\u305b\u308b\u305f\u3081\u306e\u7cfb\u7d71\u9023\u643a\u7528\u9014\u3084\u5bb6\u5ead\u8a2d\u7f6e\u7528\u9014\u306e\u3088\u3046\u306a\u5206\u6563\u578b\u96fb\u6e90\u306b\u5c55\u958b\u3059\u308b\u3053\u3068\u304c\u53ef\u80fd\u3067\u3042\u308a\u3001\u74b0\u5883\u30fb\u30a8\u30cd\u30eb\u30ae\u30fc\u554f\u984c\u306b\u8ca2\u732e\u3067\u304d\u308b\u3068\u8003\u3048\u3089\u308c\u308b\u3002\u66f4\u306b\u51fa\u529b\u304c\u6539\u5584\u3059\u308c\u3070HEV\/EV\u8eca\u8f09\u96fb\u6c60\u3068\u3057\u3066\u306e\u4f7f\u7528\u3082\u671f\u5f85\u3055\u308c\u308b\u3002 <b>(\u53c2\u8003\u6587\u732e <a href=\"http:\/\/www.cmcbooks.co.jp\/books\/t0713.php\">2009<\/a>, <a href=\"http:\/\/www3.interscience.wiley.com\/cgi-bin\/bookhome\/123277482?CRETRY=1&amp;SRETRY=0\">2010<\/a>)<\/b><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-321 size-full aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LPB_1.png\" alt=\"LPB_1\" width=\"439\" height=\"284\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LPB_1.png 439w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LPB_1-300x194.png 300w\" sizes=\"auto, (max-width: 439px) 100vw, 439px\" \/><\/p>\n<p><b>\u2605\u4f8b\u3000\u5168\u56fa\u4f53\u30ea\u30c1\u30a6\u30e0\u30dd\u30ea\u30de\u30fc\u96fb\u6c60\u306e\u88fd\u4f5c\u3068\u96fb\u6c17\u5316\u5b66\u7279\u6027\u8a55\u4fa1\u3000\uff08\u53c2\u8003\u6587\u732e\u3000<a href=\"http:\/\/www3.interscience.wiley.com\/cgi-bin\/bookhome\/123277482?CRETRY=1&amp;SRETRY=0\">2010<\/a>\uff09<\/b><br \/>\n\u30dd\u30ea\u30de\u30fc\u96fb\u89e3\u8cea\u3092\u7528\u3044\u305f\u5168\u56fa\u4f53\u96fb\u6c60\u306e\u30b3\u30f3\u30bb\u30d7\u30c8\u81ea\u4f53\u306f\u53e4\u304f\u3001\u96fb\u6c60\u304c\u5546\u696d\u5316\u3055\u308c\u305f1990\u5e74\u4ee3\u306b\u306f\u30dd\u30ea\u30de\u30fc\u96fb\u89e3\u8cea\u306e\u7814\u7a76\u304c\u76db\u3093\u306b\u884c\u308f\u308c\u3066\u3044\u308b\uff08\u6700\u521d\u306e\u30ea\u30c1\u30a6\u30e0\u4f1d\u5c0e\u6027\u30dd\u30ea\u30de\u30fc\u96fb\u89e3\u8cea\u306e\u5831\u544a\u306f1975\u5e74\uff09\u3002\u3053\u308c\u307e\u3067\u306e\u7814\u7a76\u3067\u306f\u56fa\u4f53\u96fb\u89e3\u8cea\u306e\u30a4\u30aa\u30f3\u5c0e\u96fb\u6027\u306e\u4f4e\u3055\u304c\u5fc3\u914d\u3055\u308c\u3066\u304d\u305f\u305f\u3081\u306b\u3001\u96fb\u89e3\u8cea\u306e\u30a4\u30aa\u30f3\u5c0e\u96fb\u6027\u5411\u4e0a\u3092\u76ee\u6307\u3057\u305f\u7814\u7a76\u304c\u76db\u3093\u306b\u306a\u3055\u308c\u3066\u304d\u305f\u3002\u3053\u308c\u3089\u306e\u7814\u7a76\u6210\u679c\u306b\u3088\u3063\u3066\u3001\u30dd\u30ea\u30de\u30fc\u96fb\u89e3\u8cea\u306b\u9650\u308c\u3070\u3001\u4eca\u65e5\u3067\u306f\u30dd\u30ea\u30a8\u30c1\u30ec\u30f3\u30aa\u30ad\u30b7\u30c9\u7cfb\u9ad8\u5206\u5b50\u306b\u30ea\u30c1\u30a6\u30e0\u5869\u3092\u6eb6\u304b\u3057\u305f\u3088\u3046\u306a\u96fb\u89e3\u8cea\u3067\u3001\u5ba4\u6e29\u306b\u304a\u3044\u306610<sup>-3<\/sup>\uff5e10<sup>-4<\/sup> S\/cm\u7a0b\u5ea6\u306e\u9ad8\u3044\u30a4\u30aa\u30f3\u5c0e\u96fb\u6027\u3092\u6709\u3059\u308b\u6750\u6599\u304c\u958b\u767a\u3055\u308c\u3066\u3044\u308b\u3002<br \/>\n\u3057\u304b\u3057\u3001\u30dd\u30ea\u30de\u30fc\u96fb\u89e3\u8cea\u306e\u30a4\u30aa\u30f3\u5c0e\u96fb\u6027\u6700\u9069\u5316\u304c\u9032\u3081\u3089\u308c\u3066\u3044\u308b\u4e00\u65b9\u3067\u3001\u30b7\u30b9\u30c6\u30e0\u3068\u3057\u3066\u306e\u5168\u56fa\u4f53\u96fb\u6c60\uff08\u3064\u307e\u308a\u3001\u96fb\u6975\u3068\u96fb\u89e3\u8cea\u3092\u7d44\u307f\u5408\u308f\u305b\u3066\u96fb\u6c60\u3092\u69cb\u6210\u3057\u305f\u7cfb\uff09\u306b\u3064\u3044\u3066\u3001\u7cfb\u7d71\u7684\u306b\u8a55\u4fa1\u3001\u7814\u7a76\u3057\u3066\u3044\u308b\u7814\u7a76\u30b0\u30eb\u30fc\u30d7\u306f\u5404\u56fd\u3067\u6570\u7b87\u6240\u7a0b\u5ea6\u3068\u5c11\u306a\u304f\u3001\u96fb\u6c60\u7d44\u307f\u7acb\u3066\u306e\u305f\u3081\u306e\u77e5\u8b58\u30fb\u30ce\u30a6\u30cf\u30a6\u306f\u4e0d\u8db3\u3057\u3066\u3044\u308b\u3002\u308f\u308c\u308f\u308c\u306f\u3001\u6b63\u6975\u306bLiFePO4, \u8ca0\u6975\u306b\u30ea\u30c1\u30a6\u30e0\u91d1\u5c5e\u3092\u7528\u3044\u305f\u96fb\u6c60\u306e\u88fd\u4f5c\u6cd5\u3092\u691c\u8a0e\u3057\u3001\u5ba4\u6e29\u306710<sup>-4<\/sup> S\/cm\u7a0b\u5ea6\u306e\u4f1d\u5c0e\u6027\u3092\u6301\u3063\u305f\u56fa\u4f53\u96fb\u89e3\u8cea\u3092\u7528\u3044\u305f\u5168\u56fa\u4f53\u96fb\u6c60\u3067\u3082\u3001200\u30b5\u30a4\u30af\u30eb\uff08\u653e\u96fb\uff15\u6642\u9593\/\u30b5\u30a4\u30af\u30eb\u3001\u534a\u5e74\u7a0b\u5ea6\uff09\u3092\u8d85\u3048\u308b\u5b89\u5b9a\u3057\u305f\u96fb\u6c60\u306e\u88fd\u4f5c\u6cd5\u3092\u78ba\u7acb\u3057\u305f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-322 aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LPB_2.png\" alt=\"LPB_2\" width=\"464\" height=\"400\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LPB_2.png 464w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LPB_2-300x259.png 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LPB_2-348x300.png 348w\" sizes=\"auto, (max-width: 464px) 100vw, 464px\" \/><\/p>\n<p><b>\u2605\u4f8b\u3000\u30ea\u30c1\u30a6\u30e0\u4f1d\u5c0e\u6027\u30dd\u30ea\u30de\u30fc\u96fb\u89e3\u8cea\u306e\u30ea\u30c1\u30a6\u30e0\u8f38\u9001\u7279\u6027\u3000\uff08\u53c2\u8003\u6587\u732e\u3000<a href=\"http:\/\/www3.interscience.wiley.com\/journal\/122465800\/abstract\">2009<\/a>\uff09<\/b><br \/>\n\u30dd\u30ea\u30de\u30fc\u96fb\u89e3\u8cea\u306e\u30a4\u30aa\u30f3\u5c0e\u96fb\u6027\u3092\u9ad8\u3081\u308b\u305f\u3081\u306b\u3001\u53ef\u5851\u5264\u3068\u547c\u3070\u308c\u308b\u30aa\u30ea\u30b4\u30de\u30fc\u3092\u96fb\u89e3\u8cea\u306b\u6dfb\u52a0\u3059\u308b\u624b\u6cd5\u304c\u3042\u308b\u3002\u71b1\u7279\u6027\u306b\u3059\u3050\u308c\u305f13\u65cf\u30a2\u30eb\u30b3\u30ad\u30b7\u30c9\u3092\u53ef\u5851\u5264\u306b\u3057\u305f\u30dd\u30ea\u30de\u30fc\u96fb\u89e3\u8cea\u306fAC\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u6cd5\u306b\u3088\u3063\u3066\u4f1d\u5c0e\u5ea6\u304c\uff11\u6841\u7a0b\u5ea6\u5411\u4e0a\u3059\u308b\u3053\u3068\u304c\u78ba\u8a8d\u3055\u308c\u3066\u3044\u308b\u3002\u3057\u304b\u3057\u306a\u304c\u3089\u3001\u30dd\u30ea\u30de\u30fc\u96fb\u89e3\u8cea\u4e2d\u306e\u30a4\u30aa\u30f3\u4f1d\u5c0e\u5ea6\u306f\u3001\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u3060\u3051\u3067\u306f\u306a\u304f\u30a2\u30cb\u30aa\u30f3\u3082\u4f1d\u5c0e\u306b\u95a2\u4e0e\u3059\u308b\u305f\u3081\u3001\u5f93\u6765\u306eAC\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u6cd5\u3067\u30a4\u30aa\u30f3\u4f1d\u5c0e\u5ea6\u3092\u8abf\u3079\u3066\u3082\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u306e\u6b63\u5473\u306e\u4f1d\u5c0e\u5ea6\u3092\u5f97\u308b\u3053\u3068\u306f\u96e3\u3057\u3044\u3002\u3000\u308f\u308c\u308f\u308c\u306f\u3001\u30dd\u30ea\u30de\u30fc\u4e2d\u306e\u7c92\u5b50\u306e\u62e1\u6563\u73fe\u8c61\u3092AC\u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u6cd5\u3068\u78c1\u5834\u52fe\u914dNMR\u6cd5\u3067\u8abf\u3079\u308b\u3053\u3068\u3067\u3001\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u3068\u30a2\u30cb\u30aa\u30f3\u306e\u5bc4\u4e0e\u3092\u5206\u96e2\u3057\u3001\u8f38\u7387\u304a\u3088\u3073\u5869\u89e3\u96e2\u5ea6\u3092\u7b97\u51fa\u3057\u305f\u3002\u305d\u306e\u7d50\u679c\u300113\u65cf\u30a2\u30eb\u30b3\u30ad\u30b7\u30c9\u3067\u306f\u3001\u5168\u30a4\u30aa\u30f3\u5c0e\u96fb\u6027\u306e\u5411\u4e0a\u306b\u52a0\u3048\u3066\u5869\u89e3\u96e2\u5ea6\u304a\u3088\u3073\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u8f38\u7387\u304c\u5411\u4e0a\u3059\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3057\u305f\u3002\u3053\u308c\u306f\u300113\u65cf\u30a2\u30eb\u30b3\u30ad\u30b7\u30c9\u306e\u30eb\u30a4\u30b9\u9178\u6027\u304c\u30a2\u30cb\u30aa\u30f3\u3068\u76f8\u4e92\u4f5c\u7528\u3059\u308b\u305f\u3081\u3060\u3068\u8003\u3048\u3089\u308c\u308b\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-323 size-full aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LPB_3.png\" alt=\"LPB_3\" width=\"610\" height=\"636\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LPB_3.png 610w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LPB_3-288x300.png 288w\" sizes=\"auto, (max-width: 610px) 100vw, 610px\" \/><\/p>\n<table border=\"0\" width=\"700\" cellspacing=\"0\" cellpadding=\"0\">\n<tbody>\n<tr>\n<td colspan=\"2\"><b>\u2605\u4f8b\u3000\u5168\u56fa\u4f53\u578b\u30ea\u30c1\u30a6\u30e0\u30dd\u30ea\u30de\u30fc\u96fb\u6c60\u306e\u30b5\u30a4\u30af\u30eb\u52a3\u5316\u89e3\u6790\u3000\uff08\u53c2\u8003\u6587\u732e\u3000<a href=\"http:\/\/www3.interscience.wiley.com\/journal\/122208782\/abstract\">2009<\/a> <a href=\"http:\/\/pubs.rsc.org\/en\/Content\/ArticleLanding\/2010\/EE\/C0EE00266F\">2010<\/a>.\uff09<\/b><br \/>\n\u5927\u578b\u96fb\u6c60\u3092\u5fd7\u5411\u3057\u305f\u5168\u56fa\u4f53\u578b\u30ea\u30c1\u30a6\u30e0\u30dd\u30ea\u30de\u30fc\u96fb\u6c60\u3092\u5b9f\u7528\u5316\u3059\u308b\u305f\u3081\u306b\u306f\u3001\u9ad8\u3044\u30b5\u30a4\u30af\u30eb\u8010\u4e45\u6027\uff08\u5bff\u547d\u7279\u6027\uff09\u304c\u5fc5\u8981\u3067\u3042\u308b\u3002\u3057\u304b\u3057\u3001\u3053\u308c\u307e\u3067\u306b\u4f5c\u6210\u3057\u305f\u96fb\u6c60\u306f\u3001\u4e00\u5b9a\u671f\u9593\u306e\u5b89\u5b9a\u5145\u653e\u96fb\u3057\u305f\u5f8c\u3001\u6025\u901f\u306b\u52a3\u5316\u3057\u3066\u3044\u304f\u3068\u3044\u3046\u73fe\u8c61\u304c\u89b3\u6e2c\u3055\u308c\u305f\u3002\u308f\u308c\u308f\u308c\u306f\u3001\u96fb\u6c17\u5316\u5b66\u6e2c\u5b9a\u3001\u96fb\u5b50\u9855\u5fae\u93e1\u89b3\u5bdf\u3001NMR\u6e2c\u5b9a\u306a\u3069\u306e\u8af8\u6280\u8853\u3092\u4f75\u7528\u3057\u3066\u3001\u96fb\u6975\uff5c\u96fb\u89e3\u8cea\u754c\u9762\u306e\u53cd\u5fdc\u304c\u52a3\u5316\u3068\u6df1\u304f\u76f8\u95a2\u3057\u3066\u3044\u308b\u3053\u3068\u3092\u898b\u51fa\u3057\u305f\u3002\u3053\u308c\u306f\u3001\u5168\u56fa\u4f53\u96fb\u6c60\u306e\u53cd\u5fdc\u304c\u6db2\u7cfb\u96fb\u89e3\u8cea\u3068\u306f\u7570\u306a\u308a\u56fa\u4f53\uff5c\u56fa\u4f53\u754c\u9762\u3067\u306e\u30a4\u30aa\u30f3\u4ea4\u63db\u306b\u306a\u308b\u3053\u3068\u3068\u95a2\u9023\u3057\u3066\u3044\u308b\u305f\u3081\u3001\u672c\u7814\u7a76\u306e\u6210\u679c\u306b\u3088\u3063\u3066\u5168\u56fa\u4f53\u30a4\u30aa\u30cb\u30af\u30b9\u7d20\u5b50\u306b\u5171\u901a\u3057\u305f\u6750\u6599\u8a2d\u8a08\u306e\u6307\u91dd\u3092\u5f97\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u3068\u8003\u3048\u3066\u3044\u308b\u3002<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-324 size-full aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LPB_4.png\" alt=\"LPB_4\" width=\"613\" height=\"227\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LPB_4.png 613w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LPB_4-300x111.png 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LPB_4-500x185.png 500w\" sizes=\"auto, (max-width: 613px) 100vw, 613px\" \/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-325 size-full aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/NMRreal.jpg\" alt=\"NMRreal\" width=\"622\" height=\"327\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/NMRreal.jpg 622w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/NMRreal-300x158.jpg 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/NMRreal-500x263.jpg 500w\" sizes=\"auto, (max-width: 622px) 100vw, 622px\" \/><\/p>\n<p><strong><a name=\"a03\"><\/a>\u53cd\u5fdc\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u6e2c\u5b9a<\/strong><\/p>\n<p>\u76f8\u5b89\u5b9a\u6027\u3068\u53cd\u5fdc\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u6e2c\u5b9a\uff08\u57fa\u790e\u7814\u7a76\uff09<\/p>\n<p>\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u96fb\u6975\u6750\u6599\u306e\u5145\u653e\u96fb\u53cd\u5fdc\u306f\u3001\u30db\u30b9\u30c8\u69cb\u9020\u306e\u30c8\u30dd\u30ed\u30b8\u30fc\u5909\u5316\u306a\u3057\u306b\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u304c\u633f\u5165\u8131\u96e2\u3059\u308b\u30a4\u30f3\u30bf\u30fc\u30ab\u30ec\u30fc\u30b7\u30e7\u30f3\u53cd\u5fdc\u3067\u9032\u884c\u3059\u308b\u3002\u6bd4\u8f03\u7684\u5358\u7d14\u306b\u898b\u3048\u308b\u53cd\u5fdc\u6a5f\u69cb\u3067\u3042\u308b\u304c\u3001\u591a\u304f\u306e\u96fb\u6975\u6750\u6599\u3067\u306f\u5145\u653e\u96fb\u6df1\u5ea6\u306b\u3088\u3063\u3066\u69d8\u3005\u306a\u76f8\u8ee2\u79fb\u3092\u793a\u3059\u3002\u307e\u305f\u3053\u306e\u3088\u3046\u306a\u76f8\u8ee2\u79fb\u306f\u3001\u7d4c\u9a13\u7684\u306b\u96fb\u6c60\u6027\u80fd\u3068\u6df1\u304f\u95a2\u9023\u3057\u3066\u3044\u308b\u3053\u3068\u3082\u77e5\u3089\u308c\u3066\u3044\u308b\u3002\u3000\u76f8\u8ee2\u79fb\u306e\u30e1\u30ab\u30cb\u30ba\u30e0\u306f\u7d50\u6676\u4e2d\u3067\u306e\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u3068\u7a7a\u5b54\u30b5\u30a4\u30c8\u306e\u914d\u5217\u306b\u95a2\u9023\u3057\u3066\u3044\u308b\u3068\u8003\u3048\u3089\u308c\u3066\u304d\u305f\u304c\u3001\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u306e\u914d\u5217\u3092X\u7dda\u56de\u6298\u306a\u3069\u306e\u65b9\u6cd5\u3067\u8abf\u3079\u308b\u3053\u3068\u304c\u56f0\u96e3\u3067\u3042\u3063\u305f\u3002\u305d\u3053\u3067\u3001\u308f\u308c\u308f\u308c\u306f\u30ea\u30c1\u30a6\u30e0\u3068\u7a7a\u5b54\u306e\u914d\u7f6e\u306e\u81ea\u7531\u5ea6\u306b\u7531\u6765\u3059\u308b\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u306b\u6ce8\u76ee\u3057\u3001\u96fb\u6c17\u5316\u5b66\u7684\u5b9f\u9a13\uff08\u304a\u3088\u3073\u71b1\u6e2c\u5b9a\uff09\u3067\u53cd\u5fdc\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u3092\u6e2c\u5b9a\u3057\u3066\u3044\u308b\u3002\u66f4\u306b\u3001\u672c\u7814\u7a76\u306f\u7b2c\u4e00\u539f\u7406\u8a08\u7b97\u3084\u30e2\u30f3\u30c6\u30ab\u30eb\u30ed\u6cd5\u306b\u3088\u308b\u8a08\u7b97\u7814\u7a76\u3068\u3082\u7d50\u3073\u3064\u3051\u3066\u5b9f\u65bd\u3059\u308b\u3053\u3068\u3067\u3001\u3044\u304f\u3064\u304b\u306e\u96fb\u6975\u6750\u6599\u306b\u3064\u3044\u3066\u76f8\u8ee2\u79fb\u30e1\u30ab\u30cb\u30ba\u30e0\u3092\u539f\u5b50\u30b9\u30b1\u30fc\u30eb\u304b\u3089\u8aac\u660e\u3059\u308b\u3053\u3068\u306b\u6210\u529f\u3057\u3066\u3044\u308b\u3002<\/p>\n<p><b>\u2605\u7814\u7a76\u4f8b\u3000\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u578bLa<sub>1\/3<\/sub>NbO<sub>3<\/sub>\u6750\u6599\u3078\u306e\u30ea\u30c1\u30a6\u30e0\u633f\u5165\u53cd\u5fdc\u3068\u53cd\u5fdc\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u6e2c\u5b9a\u3000(<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jp052142r\">2005<\/a>)<\/b><br \/>\n\u8907\u6570\u306e\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u53d7\u5bb9\u30b5\u30a4\u30c8\u3092\u6301\u3064\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u578bLa<sub>1\/3<\/sub>NbO<sub>3<\/sub>\u6750\u6599\u3092\u30e2\u30c7\u30eb\u6750\u6599\u3068\u3057\u3066\u3001\u5145\u653e\u96fb\u6df1\u5ea6\u306b\u4f34\u3046\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u306e\u5206\u5e03\u3092\u53cd\u5fdc\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u6e2c\u5b9a\u306b\u3088\u3063\u3066\u691c\u8a0e\u3057\u305f\u3002\u5f97\u3089\u308c\u305f\u7d50\u679c\u304b\u3089\u3001\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u306e\u683c\u5b50\u5185\u914d\u5217\u306f\u9759\u96fb\u30dd\u30c6\u30f3\u30b7\u30e3\u30eb\u306b\u3088\u3063\u3066\u652f\u914d\u3055\u308c\u3066\u3044\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u305f\u3002<br \/>\n\u307e\u305f\u3001\u53cd\u5fdc\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u6e2c\u5b9a\u306e\u65b9\u6cd5\u305d\u306e\u3082\u306e\u306b\u3064\u3044\u3066\u3082\u691c\u8a0e\u3092\u884c\u3063\u305f\u3002\u96fb\u6c17\u5316\u5b66\u7684\u306b\u53cd\u5fdc\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u3092\u6e2c\u5b9a\u3059\u308b\u624b\u6cd5\u306f\u6e29\u5ea6\u6442\u52d5\u306b\u3088\u308b\u7de9\u548c\u304c\u5341\u5206\u901f\u3044\u3068\u4eee\u5b9a\u3057\u3066\u3044\u308b\u304c\u3001\u4e00\u65b9\u71b1\u6e2c\u5b9a\u306b\u3088\u308b\u65b9\u6cd5\u3067\u306f\u30ea\u30c1\u30a6\u30e0\u7d44\u6210\u6442\u52d5\u306b\u3088\u308b\u7de9\u548c\u304c\u5341\u5206\u901f\u3044\u3068\u4eee\u5b9a\u3057\u3066\u304a\u308a\u3001\u4e21\u8005\u306f\u76f8\u88dc\u7684\u306a\u7acb\u5834\u306b\u3042\u308b\u6e2c\u5b9a\u6cd5\u3067\u3042\u308b\u3002\u672c\u7814\u7a76\u3067\u306f\u3001\u96fb\u6c17\u5316\u5b66\u7684\u6e2c\u5b9a\u6cd5\u3082\u71b1\u7684\u6e2c\u5b9a\u6cd5\u3067\u3082\u6e2c\u5b9a\u8aa4\u5dee\u7bc4\u56f2\u5185\u306b\u4e00\u81f4\u3059\u308b\u3053\u3068\u3092\u78ba\u304b\u3081\u3001\u53cd\u5fdc\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u6e2c\u5b9a\u7d50\u679c\u306e\u59a5\u5f53\u6027\u3092\u78ba\u8a8d\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u305f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-311 size-full aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Entropy1.png\" alt=\"Entropy1\" width=\"644\" height=\"319\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Entropy1.png 644w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Entropy1-300x149.png 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Entropy1-500x248.png 500w\" sizes=\"auto, (max-width: 644px) 100vw, 644px\" \/><\/p>\n<p><b>\u2605\u7814\u7a76\u4f8b\u3000\u30b9\u30d4\u30cd\u30eb\u578bLiMn<sub>2<\/sub>O<sub>4<\/sub>\u7cfb\u6750\u6599\u306b\u304a\u3051\u308b\u79e9\u5e8f\u30fb\u7121\u79e9\u5e8f\u76f8\u8ee2\u79fb\u6a5f\u69cb\u3000(<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jp056334y\">2006<\/a>)<\/b><br \/>\n\u30b9\u30d4\u30cd\u30eb\u7cfb\u6b63\u6975\u6750\u6599LixMn2O4\u306f\u3001\u56db\u9762\u4f538a\u30b5\u30a4\u30c8\u3092\u5360\u6709\u3059\u308bLi\u304c\u30c8\u30dd\u30b1\u30df\u30ab\u30eb\u306b\u633f\u5165\u8131\u96e2\u3059\u308b\u3053\u3068\u304c\u77e5\u3089\u308c\u3066\u3044\u308b\u3002Li\u304c\u534a\u5206\u8131\u96e2\u3057\u305fLi0.5Mn2O4\u306a\u308b\u7d44\u6210\u3067\u96fb\u4f4d\u304c\u5927\u304d\u304f\u5909\u5316\u3059\u308b\u3053\u3068\u304b\u3089\u3001\u7d50\u6676\u4e2d\u3067Li\u3068\u7a7a\u5b54\u304c\u4ea4\u4e92\u306b\u6574\u5217\u3059\u308b\u65b0\u305f\u306a\u76f8\u306e\u51fa\u73fe\u304c\u63d0\u6848\u3055\u308c\u3066\u3044\u308b\u3002\u4e00\u65b9\u3067\u3001Mn\u3092Mg, Co\u3084Cr\u306a\u3069+2, +3\u4fa1\u3068\u306a\u308b\u30ab\u30c1\u30aa\u30f3\u3067\u4e00\u90e8\u7f6e\u63db\u3059\u308b\u3068\u3001\u76f8\u8ee2\u79fb\u306b\u7531\u6765\u3059\u308b\u96fb\u4f4d\u5909\u5316\u304c\u5c0f\u3055\u304f\u306a\u308a\u3001\u5145\u653e\u96fb\u53cd\u5fdc\u306e\u30b5\u30a4\u30af\u30eb\u5bff\u547d\u7279\u6027\u304c\u5411\u4e0a\u3059\u308b\u3053\u3068\u304c\u77e5\u3089\u308c\u3066\u3044\u308b\u3002\u3057\u305f\u304c\u3063\u3066\u3001\u76f8\u8ee2\u79fb\u53cd\u5fdc\u6a5f\u69cb\u3092\u89e3\u660e\u3059\u308b\u3053\u3068\u306f\u96fb\u6c60\u7279\u6027\u3092\u5411\u4e0a\u3059\u308b\u305f\u3081\u306b\u91cd\u8981\u3067\u3042\u308b\u3002<br \/>\n\u672c\u7814\u7a76\u3067\u306f\u3001\u7121\u7f6e\u63db\u4f53\u304a\u3088\u3073\u7f6e\u63db\u30b9\u30d4\u30cd\u30eb\u306e\u53cd\u5fdc\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u3092\u8a73\u3057\u304f\u8abf\u3079\u3001\u540c\u6642\u306b\u30e2\u30f3\u30c6\u30ab\u30eb\u30ed\u8a08\u7b97\u3092\u5b9f\u65bd\u3059\u308b\u3053\u3068\u3067\u76f8\u8ee2\u79fb\u6a5f\u69cb\u306e\u8a73\u7d30\u3092\u8abf\u3079\u305f\u3002\u305d\u306e\u7d50\u679c\u3001\u7f6e\u63db\u30a4\u30aa\u30f3\u306f\u3001\u5c40\u6240\u7684\u306bLi\u3092\u5f15\u304d\u4ed8\u3051\u308b\u3053\u3068\u3067\u3001Li\u3068\u7a7a\u5b54\u306e\u4ea4\u4e92\u898f\u5247\u6574\u5217\u306b\u5f71\u97ff\u3092\u4e0e\u3048\u3001\u76f8\u8ee2\u79fb\u304c\u6291\u5236\u3055\u308c\u308b\u3053\u3068\u3092\u3092\u793a\u3057\u305f\u3002\u3053\u306e\u50be\u5411\u306f\u3001\u7f6e\u63db\u30a4\u30aa\u30f3\u306e\u30a4\u30aa\u30f3\u534a\u5f84\u306b\u3088\u308b\u52b9\u679c\u3088\u308a\u3082\u30a4\u30aa\u30f3\u306e\u9178\u5316\u6570\u306b\u652f\u914d\u3055\u308c\u308b\u305f\u3081\u3001\u9759\u96fb\u76f8\u4e92\u4f5c\u7528\u304c\u898f\u5247\u914d\u5217\u306b\u5f71\u97ff\u3092\u4e0e\u3048\u308b\u3053\u3068\u304c\u660e\u3089\u304b\u306b\u306a\u3063\u305f\u3002\u3000(<a href=\"http:\/\/nakayama.web.nitech.ac.jp\/research\/rsc10_abinitio\/research-j2.htm\">\u8a08\u7b97\u306b\u3064\u3044\u3066<\/a>)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-312 size-full aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Entropy2.png\" alt=\"Entropy2\" width=\"648\" height=\"342\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Entropy2.png 648w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Entropy2-300x158.png 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Entropy2-500x264.png 500w\" sizes=\"auto, (max-width: 648px) 100vw, 648px\" \/><\/p>\n<p><b>\u2605\u7814\u7a76\u4f8b\u3000\u5408\u91d1\u7cfb\u8ca0\u6975\u6750\u6599\u306e\u76f8\u8ee2\u79fb\u6a5f\u69cb (\u53c2\u8003\u6587\u732e\u3000<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jp070397u\">2007<\/a> <a href=\"http:\/\/dx.doi.org\/10.1149\/1.2916682\">2008<\/a>)<br \/>\n<\/b>\u3000\u5408\u91d1\u8ca0\u6975Cu<sub>2<\/sub>Sb\u306e\u30ea\u30c1\u30a6\u30e0\u633f\u5165\u904e\u7a0b\u306b\u304a\u3051\u308b\u76f8\u5b89\u5b9a\u6027\u3092\u30011)X\u7dda\u56de\u6298\u6e2c\u5b9a\u30012)\u30ab\u30ed\u30ea\u30e1\u30c8\u30ea\u30fc\u306b\u3088\u308b\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u8a08\u6e2c\u30013)\u7b2c\u4e00\u539f\u7406\u6cd5\uff0b\u30e2\u30f3\u30c6\u30ab\u30eb\u30ed\u6cd5\u306b\u3088\u308a\u8a55\u4fa1\u3057\u305f\u3002\u305d\u306e\u7d50\u679c\u3001\u672a\u77e5\u306e\uff12\u3064\u306e\u8d85\u683c\u5b50\u306e\u69cb\u9020\u6c7a\u5b9a\u3092\u542b\u3080\u3001Li-Cu-Sb\u7cfb\u6750\u6599\u306e\u4e09\u5143\u76f8\u56f3\u306e\u4f5c\u6210\u306b\u6210\u529f\u3057\u305f\u3002\u307e\u305f\u3001\u30b7\u30df\u30e5\u30ec\u30fc\u30b7\u30e7\u30f3\u3068\u5b9f\u9a13\u306b\u3088\u308b\u71b1\u6319\u52d5\u306e\u4e00\u81f4\u6027\u306a\u3069\u3082\u793a\u3059\u3053\u3068\u304c\u3067\u304d\u305f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-313 size-full aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Entropy3.png\" alt=\"Entropy3\" width=\"587\" height=\"354\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Entropy3.png 587w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Entropy3-300x181.png 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Entropy3-497x300.png 497w\" sizes=\"auto, (max-width: 587px) 100vw, 587px\" \/><\/p>\n<h6><strong>\u96fb\u6975\u6750\u6599\u306e\u7d50\u6676\u30fb\u96fb\u5b50\u69cb\u9020\u89e3\u6790<a name=\"a04\"><\/a>\u96fb\u6975\u6750\u6599\u306e\u7d50\u6676\u30fb\u96fb\u5b50\u69cb\u9020\u89e3\u6790<\/strong><\/h6>\n<p>\u96fb\u6975\u6750\u6599\u306e\u7d50\u6676\u30fb\u96fb\u5b50\u69cb\u9020\u89e3\u6790\uff08\u57fa\u790e\u7814\u7a76\uff09<\/p>\n<p>\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306e\u96fb\u6c17\u5316\u5b66\u53cd\u5fdc\u3068\u305d\u306e\u7279\u6027\u3092\u7406\u89e3\u3059\u308b\u305f\u3081\u306e\u7b2c\u4e00\u6b69\u306f\u3001\u6750\u6599\u306e\u7d50\u6676\u69cb\u9020\u3068\u96fb\u5b50\u69cb\u9020\u306e\u8abf\u67fb\u3067\u3042\u308b\u3002\u9060\u56de\u308a\u306e\u3088\u3046\u3067\u3042\u308b\u304c\u3001\u7cbe\u5ea6\u306e\u9ad8\u3044\u69cb\u9020\u30c7\u30fc\u30bf\u306e\u84c4\u7a4d\u306f\u3001\u3082\u3063\u3068\u3082\u512a\u308c\u305f\u6750\u6599\u3092\u8a2d\u8a08\u3059\u308b\u624b\u304c\u304b\u308a\u3092\u4e0e\u3048\u3066\u304f\u308c\u308b\u3002\u308f\u308c\u308f\u308c\u306f\u3001X\u7dda\u56de\u6298\u6e2c\u5b9a\u3001X\u7dda\u5438\u53ce\u5206\u5149\u6cd5\u306a\u3069\u306e\u624b\u6cd5\u3092\u6d3b\u7528\u3057\u3066\u3001\u5e73\u5747\u7684\u7d50\u6676\u69cb\u9020\u3001\u5c40\u6240\u7d50\u6676\u69cb\u9020\u3001\u7d44\u6210\u3001\u9178\u5316\u72b6\u614b\u3001\u5316\u5b66\u7d50\u5408\u306a\u3069\u306e\u77e5\u898b\u3092\u6750\u6599\u304b\u3089\u62bd\u51fa\u3057\u3001\u6750\u6599\u306e\u96fb\u6c17\u5316\u5b66\u7279\u6027\u3068\u5bfe\u6bd4\u3057\u3066\u8b70\u8ad6\u3092\u3057\u3066\u3044\u308b\u3002<\/p>\n<p><b>\u2605\u7814\u7a76\u4f8b\u3000\u30aa\u30ea\u30d3\u30f3\u578bLiCoPO4\u6750\u6599\u306e\u7d50\u6676\u69cb\u9020\u3001\u96fb\u5b50\u69cb\u9020\u3068\u5145\u653e\u96fb\u7279\u6027<\/b><\/p>\n<p>\u30aa\u30ea\u30d3\u30f3\u578bLiCoPO4\u306f\u5e73\u5747\u52d5\u4f5c\u96fb\u4f4d\u304c4.8V\u7a0b\u5ea6\u3068\u65e2\u5b58\u306eLiCoO2\u306b\u6bd4\u3079\u30661V\u7a0b\u5ea6\u9ad8\u304f\u3001\u6b21\u4e16\u4ee3\u306e\u9ad8\u30a8\u30cd\u30eb\u30ae\u30fc\u5bc6\u5ea6\u578b\u96fb\u6975\u6750\u6599\u3068\u3057\u3066\u6ce8\u76ee\u3055\u308c\u3066\u3044\u308b\u3002\u672c\u7814\u7a76\u3067\u306fLi\u30a4\u30aa\u30f3\u3092\u633f\u5165\u30fb\u8131\u96e2\u3059\u308b\u9593\u306e\u7d50\u6676\u69cb\u9020\u5909\u5316\u3068\u96fb\u5b50\u69cb\u9020\u5909\u5316\u3092X\u7dda\u5438\u53ce\u5206\u5149\u6cd5\uff08XAFS)\u306b\u3088\u308a\u89e3\u6790\u3092\u884c\u3063\u305f\u3002\u307e\u305f\u7d50\u679c\u3092\u7b2c\u4e00\u539f\u7406\u8a08\u7b97\u3068\u7d44\u307f\u5408\u308f\u305b\u308b\u3053\u3068\u3067\u3001\u5b9f\u9a13\u3068\u8a08\u7b97\u306e\u7d50\u679c\u306e\u5bfe\u6bd4\u3082\u884c\u3063\u3066\u3044\u308b\u3002\uff08\u53c2\u8003\u6587\u732e<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jp050569s\"> 2005<\/a>, <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/cm049230t\">2004<\/a>)<b><br \/>\n<img loading=\"lazy\" decoding=\"async\" class=\"wp-image-319 size-full aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LiCoPO4_1.png\" alt=\"LiCoPO4_1\" width=\"480\" height=\"350\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LiCoPO4_1.png 480w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LiCoPO4_1-300x219.png 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LiCoPO4_1-411x300.png 411w\" sizes=\"auto, (max-width: 480px) 100vw, 480px\" \/><br \/>\n<\/b><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-320 size-full aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LiCoPO4_3.png\" alt=\"LiCoPO4_3\" width=\"413\" height=\"279\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LiCoPO4_3.png 413w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/LiCoPO4_3-300x203.png 300w\" sizes=\"auto, (max-width: 413px) 100vw, 413px\" \/><\/p>\n<p><b>\u2605\u7814\u7a76\u4f8b\u3000\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u578bLa1\/3NbO3\u3078\u306e\u96fb\u6c17\u5316\u5b66\u7684\u30ea\u30c1\u30a6\u30e0\u633f\u5165\u53cd\u5fdc\u3068\u5c40\u6240\u69cb\u9020\u5909\u5316\u306e\u89b3\u5bdf<\/b><br \/>\n\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u578b\u9178\u5316\u7269La1\/3NbO3\u306f\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u3092\u5438\u8535\u30fb\u653e\u51fa\u3059\u308b\u3053\u3068\u304c\u53ef\u80fd\u306a\u96fb\u6975\u6750\u6599\u306b\u306a\u308b\u3002\u5b9f\u7528\u7684\u306b\u306f\u91cd\u91d1\u5c5e\u3092\u7528\u3044\u3066\u3044\u308b\u305f\u3081\u5bb9\u91cf\u5bc6\u5ea6\u3092\u7a3c\u3050\u3053\u3068\u304c\u56f0\u96e3\u3067\u3042\u308b\u304c\u3001\u305d\u306e\u5145\u653e\u96fb\u30b5\u30a4\u30af\u30eb\u7279\u6027\u306f3V-1V\u306e\u30ab\u30c3\u30c8\u30aa\u30d5\u7bc4\u56f2\u3067\u6975\u3081\u3066\u5b89\u5b9a\u3057\u3066\u3044\u308b\u3002\u3053\u306e\u3088\u3046\u306a\u5b89\u5b9a\u3057\u305f\u30b5\u30a4\u30af\u30eb\u7279\u6027\u306e\u539f\u56e0\u3092\u7a76\u660e\u3059\u308b\u305f\u3081\u306b\u3001\u5145\u653e\u96fb\u904e\u7a0b\u306b\u304a\u3051\u308bEXAFS\u6e2c\u5b9a\u30fb\u89e3\u6790\u3092\u884c\u3063\u305f\u3002\uff08\u53c2\u8003\u6587\u732e <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jp034262%2B\">2003<\/a>, <a href=\"http:\/\/dx.doi.org\/10.1016\/j.jpowsour.2005.03.066\">2005<\/a>)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-314 size-full aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Exafs_Pero1.png\" alt=\"Exafs_Pero1\" width=\"377\" height=\"254\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Exafs_Pero1.png 377w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Exafs_Pero1-300x202.png 300w\" sizes=\"auto, (max-width: 377px) 100vw, 377px\" \/><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-317 size-full aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Exafs_Pero4.png\" alt=\"Exafs_Pero4\" width=\"258\" height=\"256\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Exafs_Pero4.png 258w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Exafs_Pero4-150x150.png 150w\" sizes=\"auto, (max-width: 258px) 100vw, 258px\" \/><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-316 size-full aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Exafs_Pero3.png\" alt=\"Exafs_Pero3\" width=\"415\" height=\"229\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Exafs_Pero3.png 415w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Exafs_Pero3-300x166.png 300w\" sizes=\"auto, (max-width: 415px) 100vw, 415px\" \/><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-315 size-full aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Exafs_Pero2.png\" alt=\"Exafs_Pero2\" width=\"329\" height=\"207\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Exafs_Pero2.png 329w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/Exafs_Pero2-300x189.png 300w\" sizes=\"auto, (max-width: 329px) 100vw, 329px\" \/><\/p>\n<p><b>\u2605\u7814\u7a76\u4f8b\u3000\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u578bLa1\/3NbO3\u3078\u306e\u96fb\u6c17\u5316\u5b66\u7684\u30ea\u30c1\u30a6\u30e0\u633f\u5165\u53cd\u5fdc\u3068\u5c40\u6240\u69cb\u9020\u5909\u5316\u306e\u89b3\u5bdf<\/b><br \/>\n\u4e0a\u8ff0\u3057\u305f\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u578b\u9178\u5316\u7269La<sub>1\/3<\/sub>NbO<sub>3<\/sub>\u306f\u3001\u826f\u597d\u306a\u30b5\u30a4\u30af\u30eb\u7279\u6027\u4ee5\u5916\u306b\u3082\u3001\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8A\u30b5\u30a4\u30c8\u306b\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u3092\u5438\u8535\u30fb\u653e\u51fa\u3059\u308b\u65b9\u6cd5\u304c\uff12\u901a\u308a\u6709\u308b\u70b9\u3067\u30e6\u30cb\u30fc\u30af\u3067\u3042\u308b\u3002\u4e00\u3064\u306f\u3001\u96fb\u6c17\u5316\u5b66\u7684\u306b\uff08\u3064\u307e\u308a\u901a\u5e38\u306e\u5145\u653e\u96fb\u53cd\u5fdc\u3067\uff09\u30ea\u30c1\u30a6\u30e0\u633f\u5165\u3092\u3055\u305b\u308b\u65b9\u6cd5\u3067\u3042\u308a\u3001\u3082\u3046\u4e00\u3064\u306fLa3+\u3092Li+\u3067\u7f6e\u63db\u3059\u308b\u65b9\u6cd5\u3067\u3042\u308b\u3002\u524d\u8005\u306f\u9077\u79fb\u91d1\u5c5eNb\u306e\u9178\u5316\u9084\u5143\u53cd\u5fdc\u3092\u4f34\u3046\u304c\u3001\u5f8c\u8005\u306f\u4e00\u5b9a\u3067\u3042\u308b\u3002\u4e21\u8005\u306b\u304a\u3051\u308b\u30ea\u30c1\u30a6\u30e0\u633f\u5165\u53cd\u5fdc\u306b\u5bfe\u3059\u308b\u96fb\u5b50\u72b6\u614b\u5909\u5316\u3092\u8edfX\u7dda\u5438\u53ce\u5206\u5149\u6cd5\u306e\u30b9\u30da\u30af\u30c8\u30eb\u3068\u7b2c\u4e00\u539f\u7406\u8a08\u7b97\u3067\u305d\u308c\u305e\u308c\u6bd4\u8f03\u3059\u308b\u3053\u3068\u3067\u3001\u9178\u7d20\u5468\u8fba\u3067\u751f\u8d77\u3059\u308b\u96fb\u8377\u79fb\u52d5\u53cd\u5fdc\u306e\u7406\u89e3\u3092\u76ee\u6307\u3057\u305f\u3002(<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/cm020741u\">2003<\/a> <a href=\"http:\/\/journal.electrochem.jp\/jpn\/download.html?fn=v071m12p1025y2003.pdf\">2004<\/a> <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jp046062j\">2005<\/a>)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-332 size-full aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/XAS_pero1.png\" alt=\"XAS_pero1\" width=\"379\" height=\"321\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/XAS_pero1.png 379w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/XAS_pero1-300x254.png 300w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/XAS_pero1-354x300.png 354w\" sizes=\"auto, (max-width: 379px) 100vw, 379px\" \/><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-333 size-full aligncenter\" src=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/XAS_pero2.png\" alt=\"XAS_pero2\" width=\"344\" height=\"266\" srcset=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/XAS_pero2.png 344w, http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-content\/uploads\/2016\/04\/XAS_pero2-300x232.png 300w\" sizes=\"auto, (max-width: 344px) 100vw, 344px\" \/><\/p>\n<h6><\/h6>\n","protected":false},"excerpt":{"rendered":"<p>\u25a0\u3000\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306e\u6750\u6599\u7814\u7a76\uff08\u5b9f\u9a13\u7cfb\uff09 \u7814\u7a76\u80cc\u666f \u3000\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306f\u9ad8\u30a8 &hellip; <a href=\"http:\/\/nakayama.web.nitech.ac.jp\/jp\/%e7%a0%94%e7%a9%b6%e6%b4%bb%e5%8b%95\/%e5%ae%9f%e9%a8%93%e7%b3%bb%e7%a0%94%e7%a9%b6-2\/\">\u7d9a\u304d\u3092\u8aad\u3080 <span class=\"meta-nav\">&rarr;<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":116,"parent":11,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-58","page","type-page","status-publish","has-post-thumbnail","hentry"],"_links":{"self":[{"href":"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-json\/wp\/v2\/pages\/58","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-json\/wp\/v2\/comments?post=58"}],"version-history":[{"count":61,"href":"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-json\/wp\/v2\/pages\/58\/revisions"}],"predecessor-version":[{"id":2170,"href":"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-json\/wp\/v2\/pages\/58\/revisions\/2170"}],"up":[{"embeddable":true,"href":"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-json\/wp\/v2\/pages\/11"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-json\/wp\/v2\/media\/116"}],"wp:attachment":[{"href":"http:\/\/nakayama.web.nitech.ac.jp\/jp\/wp-json\/wp\/v2\/media?parent=58"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}